0000000000705841

AUTHOR

Harender Bisht

showing 2 related works from this author

Easy Route to Functionalize Iron Oxide Nanoparticles via Long-Term Stable Thiol Groups

2009

International audience; The functionalization of superparamagnetic iron oxide nanoparticles (SPIOs) by meso-2,3-dimercaptosuccinic acid (DMSA) was investigated. Under ambient conditions, the thiol groups from DMSA are not stable and do not allow a direct functionalization without storage in stringent conditions or a chemical regeneration of free thiols. In this study, we have developed a protocol based on poly(ethylene glycol) (PEG) grafting of SPIO prior to DMSA anchoring. We have observed that PEG helps to increase the stability of thiol groups under ambient conditions. The thiol functionalized SPIOs were stable under physiological pH and ionic strength as determined by Ellman's essay and…

Inorganic chemistryIron oxide02 engineering and technology010402 general chemistryFerric Compounds01 natural scienceschemistry.chemical_compoundPEG ratioElectrochemistryReactive dyeGeneral Materials ScienceSulfhydryl CompoundsSpectroscopychemistry.chemical_classificationMolecular Structure[ CHIM.INOR ] Chemical Sciences/Inorganic chemistry[CHIM.MATE]Chemical Sciences/Material chemistrySurfaces and Interfaces021001 nanoscience & nanotechnologyCondensed Matter PhysicsCombinatorial chemistry0104 chemical sciencesModels ChemicalchemistryIonic strength[ CHIM.MATE ] Chemical Sciences/Material chemistryThiolNanoparticlesSurface modificationSuccimer0210 nano-technologyEthylene glycolIron oxide nanoparticlesLangmuir
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Dispersion of titanate nanotubes for nanomedicine: comparison of PEI and PEG nanohybrids.

2014

In the present study, we report the dispersion of titanate nanotubes (TiONts) via polymer grafting (PolyEthylene Glycol, PEG) or polymer adsorption (polyethylene imine, PEI) where different TiONts/polymer ratios have been investigated. The TiONts/PEI and TiONts/PEG nanohybrids were characterized by scanning and transmission electron microscopy as well as by zeta potential measurements in order to determine both their dispersion state and stability in water (at different pH for zetametry). The nature of the chemical bonds at the surface of these nanohybrids was investigated by Fourier-transformed infrared (FTIR) spectroscopy while the grafting densities of PEG on the nanotubes were quantifie…

chemistry.chemical_classificationThermogravimetric analysisMaterials sciencetechnology industry and agriculturemacromolecular substancesPolymer adsorptionPolyethylene glycolPolymerInorganic Chemistrychemistry.chemical_compoundchemistryChemical engineeringPEG ratioPolymer chemistryZeta potentialFourier transform infrared spectroscopyDispersion (chemistry)Dalton transactions (Cambridge, England : 2003)
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