Author: Anandan Ranjani

0000000000709966

AUTHOR

Anandan Ranjani

showing 2 related works from this author

Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2′-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking an…

2016

A mononuclear cobalt(III) complex [Co(bpy)2Cl2]NO3⋅2H2O (1) (bpy = 2,2′-bipyridine) has been synthesized and crystallographically characterized. Self-assembly of the lattice water molecules from rectangular tetrameric water cluster interacts with nitrate anion along the c-axis forming a six membered hexagonal water-nitrate cluster. It presents a new mode of association of water molecules with nitrate molecules which is not predicted theoretically or found experimentally. The molecule effectively cleaves bacterial genomic DNA and shows important cytotoxicity against human hepatocarcinoma cell (HepG2).

010405 organic chemistryStereochemistrySupramolecular chemistrychemistry.chemical_elementGeneral ChemistryCrystal structure010402 general chemistry01 natural scienceshumanities22'-Bipyridine0104 chemical scienceschemistry.chemical_compoundgenomic DNAchemistryNitrateMoleculeWater clusterCobaltJournal of Chemical Sciences

researchProduct

CCDC 825244: Experimental Crystal Structure Determination

2018

Related Article: SUBRATA DAS, ANANDAN RANJANI, LOGANATHAN GAYATHRI, SUBHASISH SAHA, JORGE PASAN, DHARUMADURAI DHANASEKARAN, MOHAMMAD ABDULKADER AKBARSHA, MILAN MAJI, BHASKAR BISWAS|2016|J.Chem.Sci.(Bangalore,India)|128|1755|doi:10.1007/s12039-016-1167-0

Space GroupCrystallographybis(22'-bipyridine)-dichloro-cobalt(iii) nitrate dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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