Author: Stephane Bredeau

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AUTHOR

Stephane Bredeau

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Intramolecular coupling of acetylenic groups of bis(alkynyl)phosphanes and silanes mediated by benzynezirconocene: a route to new mono- and tricyclic…

2004

Benzo-zirconacyclohexadiene-phospha or silacyclobutene fused ring systems are easily prepared via a benzynezirconocene intermediate by means of thermolysis of Cp 2 ZrPh 2 in the presence of bis(alkynyl)phosphanes or silanes. These polyunsaturated systems are the source of a variety of new mono- or tricyclic heterocycles incorporating either one or two heteroatoms.

chemistry.chemical_classificationSilanesChemistryOrganic ChemistryHeteroatomThermal decompositionGeneral MedicinePhotochemistryRing (chemistry)BiochemistryMedicinal chemistryCoupling (electronics)chemistry.chemical_compoundC c couplingMain group elementIntramolecular forcePolymer chemistryDrug DiscoveryTricyclicTetrahedron

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