Structure and properties of epitaxial ferroelectric PbLu0.5Nb0.5O3thin films

Abstract Epitaxial thin film heterostructures of PbLu0.5Nb0.5O3 (PLuN) and La0.5Sr0.5CoO3 (LSCO) were deposited by in situ pulsed laser ablation onto MgO and LaAlO3 (100) substrates. The formation of crystalline phases, epitaxy, film-electrode-substrate orientation relationships, crystal perfection and chemical order were studied by x-ray diffraction. The structural properties were found to depend on the deposition conditions and on the substrate. The perovskite PLuN films were pseudocubic and epitaxial, with (001) planes parallel to the substrate surface. At room temperature, Au/PLuN/LSCO capacitors exhibited ferroelectric behavior and zero-field dielectric permittivity about e ≅ 210–260, …