0000000000786589
AUTHOR
Julien Salomon
Newton algorithm for Hamiltonian characterization in quantum control
We propose a Newton algorithm to characterize the Hamiltonian of a quantum system interacting with a given laser field. The algorithm is based on the assumption that the evolution operator of the system is perfectly known at a fixed time. The computational scheme uses the Crank-Nicholson approximation to explicitly determine the derivatives of the propagator with respect to the Hamiltonians of the system. In order to globalize this algorithm, we use a continuation method that improves its convergence properties. This technique is applied to a two-level quantum system and to a molecular one with a double-well potential. The numerical tests show that accurate estimates of the unknown paramete…
Discrete-valued-pulse optimal control algorithms: Application to spin systems
International audience; This article is aimed at extending the framework of optimal control techniques to the situation where the control field values are restricted to a finite set. We propose generalizations of the standard GRAPE algorithm suited to this constraint. We test the validity and the efficiency of this approach for the inversion of an inhomogeneous ensemble of spin systems with different offset frequencies. It is shown that a remarkable efficiency can be achieved even for a very limited number of discrete values. Some applications in nuclear magnetic resonance are discussed.