0000000000791324
AUTHOR
J. B. Patin
Chemical investigation of hassium (element 108).
The periodic table provides a classification of the chemical properties of the elements. But for the heaviest elements, the transactinides, this role of the periodic table reaches its limits because increasingly strong relativistic effects on the valence electron shells can induce deviations from known trends in chemical properties. In the case of the first two transactinides, elements 104 and 105, relativistic effects do indeed influence their chemical properties, whereas elements 106 and 107 both behave as expected from their position within the periodic table. Here we report the chemical separation and characterization of only seven detected atoms of element 108 (hassium, Hs), which were…
Liquid-scintillation detection of preseparated 257Rf with the SISAK-system
Abstract The fast liquid–liquid extraction system SISAK with continuous liquid scintillation detection was coupled to the Berkeley Gas-filled Separator to enable studies of the chemical properties of α -decaying transactinide elements. The preseparated transactinide 257Rf (4.7 s), was transported via a He/KCl-jet directly into the scintillation solution. This permitted the first unambiguous detection of transactinide atoms by the means of the α -liquid scintillation detectors of the SISAK-system. During the experiment, 89 257Rf atoms were observed. The type of events observed correspond well with the expectations based on half-lives, decay branches and transport- and hold-up times. The succ…