0000000000798104

AUTHOR

Silviu Constantin

0000-0003-3737-2652

showing 3 related works from this author

Calcite Mg and Sr partition coefficients in cave environments: Implications for interpreting prior calcite precipitation in speleothems

2020

Abstract Trace element to Ca ratios in speleothems have emerged as important proxies that reflect local environmental conditions. However, interpretations of speleothem trace element records can be challenging due to various processes. Positive correlations between speleothem Mg/Ca and Sr/Ca have often been interpreted to reflect prior calcite precipitation (PCP), a process potentially modulated by rainfall variability. For quantitative interpretation of PCP, the distribution coefficients for Mg and Sr (DMg and DSr) are required. Here, we use ten cave monitoring calcite and drip water datasets to investigate the influence of temperature and drip water and calcite Mg/Ca and Sr/Ca ratios on s…

CalciteDolostonegeographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesChemistryTrace elementSpeleothemMineralogy010502 geochemistry & geophysicsPositive correlation01 natural sciencesPartition coefficientchemistry.chemical_compoundCaveGeochemistry and PetrologyPrecipitation0105 earth and related environmental sciencesGeochimica et Cosmochimica Acta
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Reconstruction of late Holocene autumn/winter precipitation variability in SW Romania from a high-resolution speleothem trace element record

2018

We present the first high-resolution trace element (Mg/Ca, Sr/Ca, Ba/Ca) record from a stalagmite in southwestern Romania covering the last 3.6 ka, which provides the potential for quantitative climate reconstruction. Precise age control is based on three independent dating methods, in particular for the last 250 yr, where chemical lamina counting is combined with the identification of the 20th century radiocarbon bomb peak and Th-230/U dating. Long-term cave monitoring and model simulations of drip water and speleothem elemental variability indicate that precipitation-related processes are the main drivers of speleothem Mg/Ca ratios. Calibration against instrumental climate data shows a si…

010506 paleontologygeographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesTrace elementSpeleothemStalagmiteForcing (mathematics)01 natural scienceslaw.inventionGeophysicsCaveSpace and Planetary ScienceGeochemistry and Petrologylawddc:550Earth and Planetary Sciences (miscellaneous)Institut für GeowissenschaftenRadiocarbon datingPhysical geographyPrecipitationHoloceneGeology0105 earth and related environmental sciencesEarth and Planetary Science Letters
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Physicochemical characteristics of drip waters: Influence on mineralogy and crystal morphology of recent cave carbonate precipitates

2014

Speleothems are one of the most intensively explored continental archives for palaeoclimate variability. The parameters, however, that control speleothem petrography and its changes with time and space, specifically calcite crystal morphology and carbonate mineralogy, are still poorly understood. In order to shed light on processes and their products, precipitation experiments of recent carbonate crystals on watch glasses and glass plates were performed in seven selected caves. Drip water sites were analysed for their fluid Mg/Ca molar ratio, pH, degree of saturation for calcite and aragonite and drip rates. Corresponding precipitates were analysed with respect to their mineralogy, calcite …

DolostoneCalcitegeographygeography.geographical_feature_categoryAragoniteSpeleothemMineralogyengineering.materialPetrographyCrystalchemistry.chemical_compoundchemistryGeochemistry and PetrologyengineeringCarbonateCrystal habitGeologyGeochimica et Cosmochimica Acta
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