0000000000799114
AUTHOR
Yangzhou Ma
Deposition of binder-free oxygen-vacancies NiCo2O4 based films with hollow microspheres via solution precursor thermal spray for supercapacitors
Abstract Hollow micro-/nanostructures and oxygen vacancies are highly desirable for supercapacitors due to high active surface area and outstanding electrochemical properties. In order to benefiting from the both effect, binder-free oxygen-vacancies NiCo2O4 based films with hollow microspheres were pioneering directly deposited via one kind thermal spray technology, named solution precursor thermal spray (SPTS) process. To our best knowledge, the rapid one-step SPTS route was firstly employed to synthesize and deposit NiCo2O4 films for supercapacitor applications. The CV data clearly demonstrated that the specific capacitances of more oxygen-deficient NiCo2O4 electrodes with hollow microsph…
Oxygen-deficient Co3O4 submicron porous sphere films as highly active supsercapacitor electrodes
Abstract Herein, we report Co3O4 films with different content of oxygen vacancies and shapes of particles for supercapacitor electrodes. Under the similar area ratio of OII peak in the XPS spectrum of oxygen elements, the specific capacitance of electrode films with hollow spongy-like particles (963 F/g under a scan rate of 5 mV/s) is 1.6 times higher than that of the electrodes with solid irregular particles (596 F/g), indicating the effect of particle shapes on electrochemical properties. The films composed of submicron porous spheres and containing highest content of oxygen vacancies exhibited the specific capacitances as high as 1700 F/g under the scan rate of 5 mV/s. By contrast, after…
Novel chemical reaction co-precipitation method for the synthesis of apatite-type lanthanum silicate as an electrolyte in SOFC
Abstract Apatite-type lanthanum silicates have promising performance as electrolyte materials for IT-SOFC. A novel co-precipitation method, based on chemical reaction, is employed in the synthesis process. The reaction products: La(OH) 3 and SiO 2 are used as precursors of apatite synthesis process. The precursors are mixed in molecular scale which provide much conducive to formation reaction. The pure apatite phase composition is obtained with quite moderate temperature of 700 °C for 6 h which shows considerable ionic conductivity performance. The conductivity decreases when you increase the calcination temperature in according with XRD measurement. The XRD measurement shows the presence o…
Oxygen-defective ZnO films with various nanostructures prepared via a rapid one-step process and corresponding photocatalytic degradation applications.
Abstract The deposition of oxygen-defective ZnO films exhibiting varied nanostructures via Solution Precursor Plasma Spray (SPPS) route, a one-step, minute-scaled duration and large scale method, is reported. The in situ formation of oxygen vacancies in ZnO films was confirmed by UV–Visible, Raman and photoluminescence (PL) spectroscopy and the as-prepared samples exhibit a bandgap as low as 3.02 eV. Density functional theory (DFT) simulation demonstrates that the polarization of ZnO is enhanced by the created oxygen vacancies, leading to substantially improved photocatalytic activity. The comparative experiments also revealed that forming and preserving appropriate ZnO precursor clusters i…