0000000000819168
AUTHOR
J. Koschikowski
An integrated approach for HCl and metals recovery from waste pickling solutions: pilot plant design and operations
Continuous regeneration of industrial pickling solutions and recovery of valuable materials are implemented in a pilot-scale plant including diffusion dialysis, membrane distillation and reactive precipitation units. The main results of the preliminary assessment of on site operation are presented. Different hydrochloric acid concentration and metals composition were investigated and the performance of the system were analysed in terms of quality of recovered compounds, energy efficiency and environmental footprint.
Design, construction and operational results of a pilot plant for the treatment and valorization of pickling waste solutions
An innovative hybrid technology for both minimizing the waste production and optimizing the pickling process through the continuous control of pickling baths composition has been proposed by means of a pilot-plant installed at the Tecnozinco Srl, Carini (PA) hot-dip galvanizing plant. The recovery process has been accomplished by coupling a diffusion dialysis (DD), where HCl is recovered, a membrane distillation (MD), where HCl is concentrated, and a reactive precipitation (RP), where metal ions are recovered as iron hydroxide and ammonium/zinc chloride solution, to be used in the fluxing baths of the plant. The pilot plant was commissioned and operated using synthetic HCl solutions first a…