Author: Ismael Mullor-ruíz

0000000000822676

AUTHOR

Ismael Mullor-ruíz

Peptide metal-organic frameworks under pressure: flexible linkers for cooperative compression

We investigate the structural response of a dense peptide metal-organic framework using in situ powder and single-crystal X-ray diffraction under high-pressures. Crystals of Zn(GlyTyr)2 show a reversible compression by 13% in volume at 4 GPa that is facilitated by the ability of the peptidic linker to act as a flexible string for a cooperative response of the structure to strain. This structural transformation is controlled by changes to the conformation of the peptide, which enables a bond rearrangement in the coordination sphere of the metal and changes to the strength and directionality of the supramolecular interactions specific to the side chain groups in the dipeptide sequence. Compar…

research product

CCDC 1588161: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588164: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588162: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588165: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588166: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588163: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

CCDC 1588160: Experimental Crystal Structure Determination

Related Article: José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo|2018|Dalton Trans.|47|10654|doi:10.1039/C8DT01765D

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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