0000000000842991
AUTHOR
Diogo A. Gálico
Triplet-State Position and Crystal-Field Tuning in Opto‐Magnetic Lanthanide Complexes : Two Sides of the Same Coin
Lanthanide complex‐based luminescence thermometry and single‐molecule magnetism are two effervescent research fields, owing to the great promise they hold from an application standpoint. The high thermal sensitivity achievable, their contactless nature, along with sub‐micrometric spatial resolution make these luminescent thermometers appealing for accurate temperature probing in miniaturized electronics. To that end, single‐molecule magnets (SMMs) are expected to revolutionize the field of spintronics, thanks to the improvements made in terms of their working temperature – now surpassing that of liquid nitrogen – and manipulation of their spin state. Hence, the combination of such opto‐magn…
A Luminescent Thermometer Exhibiting Slow Relaxation of the Magnetization: Toward Self-Monitored Building Blocks for Next-Generation Optomagnetic Devices
The development and integration of Single-Molecule Magnets (SMMs) into molecular electronic devices continue to be an exciting challenge. In such potential devices, heat generation due to the electric current is a critical issue that has to be considered upon device fabrication. To read out accurately the temperature at the submicrometer spatial range, new multifunctional SMMs need to be developed. Herein, we present the first self-calibrated molecular thermometer with SMM properties, which provides an elegant avenue to address these issues. The employment of 2,2′-bipyrimidine and 1,1,1-trifluoroacetylacetonate ligands results in a dinuclear compound, [Dy2(bpm)(tfaa)6], which exhibits slow …
Probing optical and magnetic properties via subtle stereoelectronic effects in mononuclear DyIII-complexes
Tapping into the secondary coordination environment of mononuclear DyIII-complexes leads to drastic changes in luminescence and magnetism. Visualization of effects induced by stereoelectronics on the opto-magnetic properties was achieved through subtle modifications in the ligand framework.
Triplet‐State Position and Crystal‐Field Tuning in Opto‐Magnetic Lanthanide Complexes: Two Sides of the Same Coin
Lanthanide-complex-based luminescence thermometry and single-molecule magnetism are two effervescent fields of research, owing to the great promise they hold from an application standpoint. The high thermal sensitivity achievable, their contactless nature, along with sub-micrometric spatial resolution make these luminescent thermometers appealing for accurate temperature probing in miniaturised electronics. To that end, single-molecule magnets (SMMs) are expected to revolutionise the field of spintronics, thanks to the improvements made in terms of their working temperature-now surpassing that of liquid nitrogen-and manipulation of their spin state. Hence, the combination of such opto-magne…
CCDC 2081829: Experimental Crystal Structure Determination
Related Article: Alexandros A. Kitos, Diogo A. Gálico, Niki Mavragani, Raúl Castañeda, Jani O. Moilanen, Jaclyn L. Brusso, Muralee Murugesu|2021|Chem.Commun.|57|7818|doi:10.1039/D1CC02407H
CCDC 1859276: Experimental Crystal Structure Determination
Related Article: Dylan Errulat, Riccardo Marin, Diogo A. Gálico, Katie L. M. Harriman, Amelie Pialat, Bulat Gabidullin, Fernando Iikawa, Odilon D. D. Couto, Jani O. Moilanen, Eva Hemmer, Fernando A. Sigoli, Muralee Murugesu|2019|ACS Cent.Sci.|5|1187|doi:10.1021/acscentsci.9b00288
CCDC 1859277: Experimental Crystal Structure Determination
Related Article: Dylan Errulat, Riccardo Marin, Diogo A. Gálico, Katie L. M. Harriman, Amelie Pialat, Bulat Gabidullin, Fernando Iikawa, Odilon D. D. Couto, Jani O. Moilanen, Eva Hemmer, Fernando A. Sigoli, Muralee Murugesu|2019|ACS Cent.Sci.|5|1187|doi:10.1021/acscentsci.9b00288