0000000000845441

AUTHOR

Aleksander Herman

Syntheses, spectroscopic and structural properties of phenoxysilyl compounds : X-ray structures, FT-IR and DFT calculations

Abstract The reaction of silicon disulfide with alkylphenols yields tetraphenoxysilane, cyclodisilthiane and silanethiol. The outcome of the reaction depends on the presence of the steric hindrance in the ortho position on the reacting phenol. New products of the reaction of silicon disulfide with phenols are characterized by FT-IR, NMR, X-ray diffraction and DFT calculations. The intramolecular interactions in the compounds are mainly XH---π (X = C, S) whereas the intermolecular interactions are either very weak CH---π/CH---O contacts found in aryloxysilane or electrostatic dipole–dipole attraction in cyclodisilthiane and silanethiol. The S–H---π interactions in the obtained silanethiol ar…

research product

CCDC 917843: Experimental Crystal Structure Determination

Related Article: Agnieszka Jabłońska, Łukasz Ponikiewski, Krzysztof Ejsmont, Aleksander Herman, Anna Dołęga|2013|J.Mol.Struct.|1054|359|doi:10.1016/j.molstruc.2013.09.058

research product

CCDC 917842: Experimental Crystal Structure Determination

Related Article: Agnieszka Jabłońska, Łukasz Ponikiewski, Krzysztof Ejsmont, Aleksander Herman, Anna Dołęga|2013|J.Mol.Struct.|1054|359|doi:10.1016/j.molstruc.2013.09.058

research product

CCDC 917841: Experimental Crystal Structure Determination

Related Article: Agnieszka Jabłońska, Łukasz Ponikiewski, Krzysztof Ejsmont, Aleksander Herman, Anna Dołęga|2013|J.Mol.Struct.|1054|359|doi:10.1016/j.molstruc.2013.09.058

research product