0000000000848736

AUTHOR

Mayra Rengifo Carrillo

showing 2 related works from this author

Oleanane-type glycosides from Pittosporum tenuifolium “variegatum” and P. tenuifolium “gold star”

2017

Abstract The phytochemical study of two cultivars of Pittosporum tenuifolium Banks & Sol. ex Gaertn, “variegatum” and “gold star”, led to the isolation of eight oleanane-type glycosides: seven previously undescribed and a known one. Their aglycons are oxygenated oleanane derivatives as barringtogenol C, camelliagenin A, hederagenin, and 22α-hydroxyoleanolic acid. Their structures were established by 2D NMR spectroscopic techniques and mass spectrometry as 3-O-β-D-galactopyranosyl-(1 → 2)-[α-L-arabinopyranosyl-(1 → 3)]-β-D-glucuronopyranosyl-21-O-angeloyl-22-O-acetylbarringtogenol C, 3-O-β-D-galactopyranosyl-(1 → 2)-[α-L-arabinopyranosyl-(1 → 3)]-β-D-glucuronopyranosyl-21,22-di-O-angeloylbar…

StereochemistryChemical structurePlant ScienceHorticulture01 natural sciencesBiochemistrychemistry.chemical_compoundGlycosidesOleanolic AcidRosalesMolecular BiologyOleananechemistry.chemical_classificationMolecular StructurebiologyPlant Extracts010405 organic chemistryPittosporum tenuifoliumGlycosideGeneral MedicineSaponinsPittosporumbiology.organism_classification0104 chemical sciences010404 medicinal & biomolecular chemistryHederageninchemistryPhytochemicalChemotaxonomyPhytochemistry
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Two New Oleanane-type Saponins from Hydrocotyle multifida

2018

A phytochemical study of a Venezuelan species Hydrocotyle multifida led to the isolation of five oleanane-type glycosides: two previously undescribed and three known ones. Their structures were established by 2D NMR spectroscopic techniques and mass spectrometry as 3- O-β-D-galactopyranosyl-(1→2)-[α-L-arabinopyranosyl-(1→3)]-β-D-glucuronopyranosyloleanolic acid and 3- O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl-(1→2)-β-D-glucuronopyrano-syloleanolic acid. These results represent a significative contribution to the chemotaxonomy of the Hydrocotyle genus.

Pharmacologychemistry.chemical_classificationbiologyTraditional medicine010405 organic chemistryChemistryGlycosidePlant ScienceGeneral Medicinebiology.organism_classification01 natural sciences0104 chemical sciences010404 medicinal & biomolecular chemistrychemistry.chemical_compoundType (biology)Complementary and alternative medicinePhytochemicalDrug DiscoveryHydrocotyleAraliaceaeOleananeNatural Product Communications
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