0000000000849046

AUTHOR

Lisa B. Weiss

showing 2 related works from this author

Spatial Demixing of Ring and Chain Polymers in Pressure-Driven Flow

2019

We investigate mixtures of ring and linear polymers in solution at various number ratios, ranging from pure chains to pure rings, and at densities around the overlap concentration. In bulk and at r...

chemistry.chemical_classification0303 health sciencesMaterials scienceMathematics::Commutative AlgebraPolymers and PlasticsLinear polymerOrganic ChemistryPressure-driven flow02 engineering and technologyPolymer021001 nanoscience & nanotechnologyRing (chemistry)Inorganic Chemistry03 medical and health sciencesChain (algebraic topology)chemistryChemical physicsMaterials Chemistry0210 nano-technology030304 developmental biologyMacromolecules
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Topology-Sensitive Microfluidic Filter for Polymers of Varying Stiffness

2017

The separation of polymers based on their size, rigidity, and topology is an essential but also highly challenging task for nanoscience and engineering. Using hybrid molecular dynamics simulations that correctly take into account hydrodynamics, we have designed microfluidic channels for separating linear from ring polymers in dilute solutions. We establish that the transport velocity of the polymers is independent of their topology and rigidity when the channel walls are smooth and repulsive. However, when the walls are decorated with attractive spots arranged on lines parallel to the flow, ring polymers exhibit an order of magnitude higher transport velocity compared to linear chains. The …

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsOrganic ChemistryMicrofluidicsStiffness02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnologyTopology01 natural sciences0104 chemical sciencesCondensed Matter::Soft Condensed MatterInorganic ChemistryMolecular dynamicsRigidity (electromagnetism)chemistryMicrofluidic channelNano-Materials Chemistrymedicinemedicine.symptom0210 nano-technologyOrder of magnitudeACS Macro Letters
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