0000000000850633
AUTHOR
David P. Gillikin
Unraveling environmental histories from skeletal diaries — Advances in sclerochronology
High-resolution proxy archives from aquatic settings are essential to better understand processes and mechanisms of global change. During the last decade, it has become increasingly evident that calcified tissues of bivalve mollusks and cold-water corals, in particular, can significantly increase our knowledge of seasonal to multi-decadal paleoclimate and paleoenvironmental variability in the extratropical oceans and coastal marine settings. Daily, tidal, fortnightly and annual growth patterns of periodically formed skeletal hard parts provide a means to place the proxy record in a precise temporal context. Their extreme longevity coupled with the running similarity between growth increment…
Effect of organic matrices on the determination of the trace element chemistry (Mg, Sr, Mg/Ca, Sr/Ca) of aragonitic bivalve shells (<i>Arctica islandica</i>)&mdash;Comparison of ICP-OES and LA-ICP-MS data
The element chemistry of biogenic carbonates can provide important data on past environments. However, the Sr/Ca and Mg/Ca ratios as well as the Mg and Sr concentrations of biological carbonates, especially aragonitic bivalves often depart from apparent thermodynamic equilibrium. When measured in situ by means of LA-ICP-MS, the Mg concentration is often substantially enriched (two- to threefold) near the organic-rich, annual growth lines. To test the hypothesis that some organic components exert a major influence on the skeletal metal content, the element chemistry of different shell components (insoluble organic matrix, IOM; dissolved CaCO3 and soluble organics, SOM) of Arctica islandica w…