0000000000855755
AUTHOR
Alexander G. Tskhovrebov
cis-Dichloridobis(2-isocyanophenyl 4-methoxybenzoate)palladium(II) chloroform monosolvate
In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the PdII atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyanophenyl ligands. The molecular conformation is stabilized by π–π stacking interactions [shortest centroid–centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C—H...O and C—H...Cl interactions involving the chloroform solvent molecules.
Attractive halogen···halogen interactions in crystal structure of trans-dibromogold(III) complex
Abstract A synthesis of the trans-dibromogold(III) t-Bu-Xantphos complex and its self-assembly into infinite 1-dimensional chain in the solid state is reported. The new complex characterized using elemental analyses (C, H, N), ESI-MS, 1H and 13C NMR techniques and X-ray diffraction analysis. Results of DFT calculations followed by the topological analysis of the electron density distribution within the framework of QTAIM method at the ωB97XD/DZP-DKH level of theory reveal that strength of attractive intermolecular non-covalent interactions Br···Br in the crystal is 1.2–1.6 kcal/mol.
Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies
Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO2 results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.
CCDC 1577120: Experimental Crystal Structure Determination
Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072
CCDC 1577119: Experimental Crystal Structure Determination
Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072
CCDC 1577118: Experimental Crystal Structure Determination
Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072
CCDC 1577121: Experimental Crystal Structure Determination
Related Article: Alexander G. Tskhovrebov, Anna A. Vasileva, Richard Goddard, Tina Riedel, Paul J. Dyson, Vladimir N. Mikhaylov, Tatiyana V. Serebryanskaya, Viktor N. Sorokoumov, Matti Haukka|2018|Inorg.Chem.|57|930|doi:10.1021/acs.inorgchem.8b00072