6533b837fe1ef96bd12a2884
RESEARCH PRODUCT
cis-Dichloridobis(2-isocyanophenyl 4-methoxybenzoate)palladium(II) chloroform monosolvate
Matti HaukkaAlexander G. Tskhovrebovsubject
Metal-Organic PapersCrystallographyChemistryStackingchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsBioinformaticsMedicinal chemistrychloroform solvent moleculesSolventCrystalchemistry.chemical_compoundmolecular conformationQD901-999Atomsingle-crystal X-ray studyGeneral Materials ScienceBenzeneta116crystal packingCoordination geometryPalladiumdescription
In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the PdII atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyanophenyl ligands. The molecular conformation is stabilized by π–π stacking interactions [shortest centroid–centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C—H...O and C—H...Cl interactions involving the chloroform solvent molecules.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-01-01 | Acta Crystallographica. Section E: Structure Reports Online |