0000000000869315

AUTHOR

Douglass F. Taber

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Synthesis of Natural Products By Rhodium-Mediated Intramolecular C-H Insertion

1998

The strategic advantages of the Rh-mediated intramolecular C–H insertion, which has been used as the key step in several natural product syntheses, are described here. The most recent such synthesis is the elegant route to (+)-morphine shown below.

chemistry.chemical_compoundC c couplingNatural productchemistryStereochemistryIntramolecular forceOrganic Chemistrychemistry.chemical_elementGeneral ChemistryCatalysisNatural (archaeology)RhodiumChemistry - A European Journal
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