0000000000869790

AUTHOR

Elena Salvador

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A dinucleating ligand which promotes DNA cleavage with one and without a transition metal ion.

2013

The dinucleating ligand L (1,3-bis[bis(pyridin-2-ylmethyl)amino]propan-2-ol) combined with metal ions efficiently cleaves DNA when M : L is 1 : 1 (M = Co(II) or Fe(III)) at pH 5.5–7.0, with free L being more active at acidic pH than when bound to Zn(II), Cu(II) or Ni(II) at neutral pH.

LigandPyridinesMetal ions in aqueous solutionInorganic chemistryMetals and AlloysGeneral ChemistryDNALigandsTransition metal ionsCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryDna cleavageCoordination ComplexesPolymer chemistryMaterials ChemistryCeramics and CompositesTransition ElementsNeutral phDNA CleavageDNAPlasmidsChemical communications (Cambridge, England)
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