Symmetry-species conversion in CD3systems

1993

The rates for symmetry-species conversion of CD3 groups are calculated using a model in which the interaction between the quadrupolar moment of the deuterons with electric-field gradient at the site of the nucleus causes symmetry-changing transitions. Just the same phonons are considered for energy conservation as are used to describe the temperature dependence of inelastic neutron scattering experiments. For the conversion rate, a similar temperature dependence is found as has already been obtained for CH3. For temperatures around the tunnelling energy, a behaviour is predicted for CD3 that is different from the behaviour in protonated systems according to all theories known to the authors…