Author: Javier Troyano

0000000000883874

AUTHOR

Javier Troyano

A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence

The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)] (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.

research product

CCDC 1481679: Experimental Crystal Structure Determination

Related Article: Javier Troyano, Óscar Castillo, Pilar Amo-Ochoa, Vanesa Fernández-Moreira, Carlos J. Gómez-García, Félix Zamora, Salomé Delgado|2016|J.Mater.Chem.C|4|8545|doi:10.1039/C6TC02401G

research product

CCDC 1481680: Experimental Crystal Structure Determination

Related Article: Javier Troyano, Óscar Castillo, Pilar Amo-Ochoa, Vanesa Fernández-Moreira, Carlos J. Gómez-García, Félix Zamora, Salomé Delgado|2016|J.Mater.Chem.C|4|8545|doi:10.1039/C6TC02401G

research product

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