6533b839fe1ef96bd12a67a8
RESEARCH PRODUCT
A crystalline and free-standing silver thiocarboxylate thin-film showing high green to yellow luminescence
Félix ZamoraCarlos J. Gómez-garcíaJavier TroyanoPilar Amo-ochoaSalomé DelgadoOscar CastilloVanesa Fernández-moreirasubject
LuminescenceSilverMaterials scienceThin filmsNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesMaterials ChemistryThin filmchemistry.chemical_classificationThermochromismCrystalline materialsQuímicaGeneral ChemistryPolymer021001 nanoscience & nanotechnology0104 chemical sciencesCrystallographychemistrySolubilizationFilm preparation0210 nano-technologyLuminescenceCoordination reactionsdescription
The simple direct synthesis of Cu(ii) and Ag(i) salts and thiobenzoic acid under ambient conditions allows the preparation of two bidimensional coordination polymers [M(TB)] (TB = thiobenzoate; M = Cu (1) or Ag (2)). Their electrical and luminescent properties show that these are multifunctional materials. Interestingly 1 and 2 undergo a reversible solubilization process. This unusual feature and their simple preparation allow us to prepare a crystalline and free-standing thin-film of 2, using an interfacial procedure, which shows a remarkable thermochromic luminescence.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-01 |