0000000000885132

AUTHOR

Leonas Valkunas

showing 2 related works from this author

Fluorescence quenching by trapped charge carriers in N,N-dimethylaminobenzylidene 1,3-indandione films

2010

Effects caused by the applied voltage on the steady state and time-resolved fluorescence of vacuum evaporated N,N-dimethylaminobenzylidene 1,3-indandione films sandwiched between gold and aluminium electrodes were investigated and discussed. Fluorescence enhancement and quenching as well as the fluorescence band narrowing depending on the applied voltage have been observed. Fluorescence decay and recovery take place on a time scale of tens of seconds after voltage is switched on and off. Similar fluorescence decay also takes place after switching on the excitation light. These fluorescence changes are attributed to the exciton quenching by trapped charge carriers.

Steady stateMaterials scienceQuenching (fluorescence)13-IndandioneExcitonMetals and AlloysAnalytical chemistrySurfaces and InterfacesCondensed Matter::Mesoscopic Systems and Quantum Hall EffectPhotochemistryFluorescenceSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryMaterials ChemistryCharge carrierExcitationVoltageThin Solid Films
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Impact of aggregates on excitation dynamics in transparent polymer films doped by dipolar molecules

2008

Abstract Optical properties of transparent polymer films of polymethylmethacrylate doped (up to 25 wt.%) by dipolar N , N -dimethylaminobenzylidene 1,3-indandione (DMABI) molecules were studied. Formation of DMABI nanocrystallites, increasing in their density and size with dopant concentration, was revealed by optical microscopy. Transformation of the fluorescence spectrum from the molecular-like emission (for the low dopant concentration below 1 wt.%) to highly red-shifted fluorescence corresponding to self-trapped excitons in the crystallites was observed. It was shown, that due to the resonant energy transfer in the blend, the DMABI nanocrystals can serve as efficient fluorescence marker…

chemistry.chemical_classificationResonant inductive couplingMaterials scienceDopantExcitonDopingMetals and AlloysAnalytical chemistrySurfaces and InterfacesPolymerPhotochemistryFluorescenceSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCondensed Matter::Materials ScienceNanocrystalchemistryMaterials ChemistryCrystalliteThin Solid Films
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