0000000000894303
AUTHOR
M. Jesús Hernández
Effects of a macroscopic fixed charge inhomogeneity on some membrane transport properties
Abstract The effects that a macroscopic fixed charge inhomogeneity exerts on some membrane transport properties have been theoretically analyzed. To this end, we introduce two particular inhomogeneous fixed charge distributions on the basis of previous experimental work, and the transport equations are assumed to be the Nernst-Planck equations. It is found that a macroscopic redistribution of a constant quantity of fixed charge groups can modify the observed transport properties, the two inhomogeneous membranes here considered exhibiting permselectivities different from those of otherwise identical homogeneous membranes. Although the main emphasis of the study is on the basic aspects of tra…
Flow and thixotropy of non-contaminating oil drilling fluids formulated with bentonite and sodium carboxymethyl cellulose
Abstract A study has been made of low-contaminating oil drilling mud in water base, composed of bentonite, at concentrations in the range of 6–12% (w/w), and sodium carboxymethyl cellulose at two different concentrations. Flow analysis yielded an empirical formula indicating shear stress as a function of the formulation concentrations of bentonite and sodium carboxymethyl cellulose, stirring time and shear rate. To study the thixotropy of the different formulations the cycles' method has been used. Calculations were made of the thixotropic areas, obtaining a semi-empirical equation for these areas. The results are analyzed on the base of relative thixotropic area and total relative thixotro…