0000000000894498

AUTHOR

Florence Volatron

showing 2 related works from this author

High-Quality Metal–Organic Framework Ultrathin Films for Electronically Active Interfaces

2016

Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that t…

PermalloyChemistryNanotechnology02 engineering and technologyGeneral ChemistryConductivity010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistryCatalysis0104 chemical sciencesColloid and Surface ChemistryFerromagnetismMonolayerDeposition (phase transition)Metal-organic frameworkElectronicsThin film0210 nano-technologyJournal of the American Chemical Society
researchProduct

Photo-induced magnetic bistability in a controlled assembly of anisotropic coordination nanoparticles.

2011

International audience; Anisotropic coordination nanoparticles of the photomagnetic network Cs(I)(2)Cu(II)(7)[Mo(IV)(CN)(8)](4) are obtained through a surfactant-free high-yield synthetic procedure in water. These particles are organised as Langmuir-Blodgett films with a preferential orientation of the nano-objects within the film that exhibit a magnetic bistability below 20 K with a very large coercivity due to an efficient photo-transformation.

Materials scienceCondensed matter physics010405 organic chemistryMetals and AlloysNanoparticleNanotechnologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryCoercivityOrientation (graph theory)010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMagnetic bistabilityMaterials ChemistryCeramics and CompositesAnisotropy
researchProduct