6533b86dfe1ef96bd12c9653

RESEARCH PRODUCT

Photo-induced magnetic bistability in a controlled assembly of anisotropic coordination nanoparticles.

Daniela HeurtauxAlexandre GloterLaure CatalaOdile StéphanDiego RepettoCorine MathonièreFlorence VolatronTalal MallahEugenio CoronadoMiguel Clemente-león

subject

Materials scienceCondensed matter physics010405 organic chemistryMetals and AlloysNanoparticleNanotechnologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryCoercivityOrientation (graph theory)010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMagnetic bistabilityMaterials ChemistryCeramics and CompositesAnisotropy

description

International audience; Anisotropic coordination nanoparticles of the photomagnetic network Cs(I)(2)Cu(II)(7)[Mo(IV)(CN)(8)](4) are obtained through a surfactant-free high-yield synthetic procedure in water. These particles are organised as Langmuir-Blodgett films with a preferential orientation of the nano-objects within the film that exhibit a magnetic bistability below 20 K with a very large coercivity due to an efficient photo-transformation.

10.1039/c0cc04940ahttps://hal.archives-ouvertes.fr/hal-00565250