Author: Johanna Kutuniva

Uusiutuvat energiat : hiilidioksidin hyödyntäminen ja kuivamädätys

Tämän julkaisun ensimmäisessä osassa selvitetään erilaisia mahdollisuuksia hyödyntää bio- ja puukaasun ohella muodostuvaa hiilidioksidia ja erityisesti sen hyötykäyttöä kasvihuoneympäristössä. Toisessa osassa käsitellään kuivamädätysteknologiaa sekä siihen liittyviä käyttökokemuksia kirjallisuuteen ja henkilökohtaisiin haastatteluihin pohjautuen. Julkaisun tarkoituksena on tukea uusiutuvaan energiaan liittyvää tutkimus- ja kehittämistoimintaa.

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Measuring the14C content in liquid scintillators

We are going to perform a series of measurements where the 14C/12 C ratio will be measured from several liquid scintillator samples with a dedicated setup. The setup is designed with the aim of measuring ratios smaller than 10-18. Measurements take place in two underground laboratories: in the Baksan Neutrino Observatory, Russia and in the Pyhasalmi mine, Finland. In Baksan the measurements started in 2015 and in Pyhasalmi they start in the beginning of 2015. In order to fully understand the operation of the setup and its background contributions a development of simulation packages has also been started. Low-energy neutrino detection with a liquid scintillator requires that the intrinsic 1…

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"Identification of mixed bromidochloridotellurate anions in disordered crystal structures of (bdmim)2[TeX2Y4] (X, Y = Br, Cl; bdmim = 1-butyl-2,3-dimethylimidazolium) by combined application of Raman spectroscopy and solid-state DFT calculations"

Abstract The discrete mixed [TeBrxCl6−x]2− anions in their disordered crystal structures have been identified by using the phases prepared by the reaction of 1-butyl-2,3-dimethylimidazolium halogenides (bdmim)X with tellurium tetrahalogenides TeX4 (X = Cl, Br) as examples. Homoleptic (bdmim)2[TeX6] [X = Cl (1), Br (2)] and mixed (bdmim)2[TeBr2Cl4] (3), and (bdmim)2[TeBr4Cl2] (4) are formed depending on the choice of the reagents, and their crystal structures have been determined by single-crystal X-ray diffraction. The coordination environments of tellurium in all hexahalogenidotellurates are almost octahedral. Because of the crystallographic disorder, the mixed [TeBr2Cl4]2− and [TeBr4Cl2]2…

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Identification of mixed bromidochloridotellurate anions in disordered crystal structures of (bdmim)2[TeX2Y4] (X, Y = Br, Cl; bdmim = 1-butyl-2,3-dimethylimidazolium) by combined application of Raman spectroscopy and solid-state DFT calculations

The discrete mixed [TeBrxCl6−x]2− anions in their disordered crystal structures have been identified by using the phases prepared by the reaction of 1-butyl-2,3-dimethylimidazolium halogenides (bdmim)X with tellurium tetrahalogenides TeX4 (X = Cl, Br) as examples. Homoleptic (bdmim)2[TeX6] [X = Cl (1), Br (2)] and mixed (bdmim)2[TeBr2Cl4] (3), and (bdmim)2[TeBr4Cl2] (4) are formed depending on the choice of the reagents, and their crystal structures have been determined by single-crystal X-ray diffraction. The coordination environments of tellurium in all hexahalogenidotellurates are almost octahedral. Because of the crystallographic disorder, the mixed [TeBr2Cl4]2− and [TeBr4Cl2]2− anions …

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A New Low Background Laboratory in the Pyhäsalmi Mine : Towards 14C free liquid scintillator for low energy neutrino experiments

A new low background laboratory in Pyhäsalmi mine in the Central Finland has been put into operation in the beginning of 2017. The laboratory operates at the depth of 1436 m (~4100 meters of water equivalent). In this paper, we present description of the laboratory’s existing facility and background conditions. In the laboratory, a series of measurements has been started where the 14C concentration is determined from several liquid scintillator samples. A dedicated setup has been designed and constructed with the aim of measuring the 14C/12C ratio smaller than 10-18 . peerReviewed

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