0000000000918723
AUTHOR
Florencio E. Hernandez
showing 2 related works from this author
Focal squeeze in axicons
2005
The on-axis irradiance distribution of a truncated conical wavefront is evaluated in terms of the Fresnel number of the focusing geometry. In agreement with geometrical optics, a focal line of increasing intensity is generated for extremely high Fresnel numbers. Otherwise clear deviations may be observed for the position of the maximum irradiance along the optical axis. A remarkable focal squeeze appears and, for decreasing Fresnel numbers, this effect manifests stronger. An analytical formula is provided for the fast evaluation of the focal squeeze.
Unveiling Electronic Transitions in Three Novel Chiral Azo-Compounds Using Linear and Nonlinear Circular Dichroism: A Theoretical−Experimental Study
2011
Herein, we report on the experimental and theoretically study of the linear absorption, electronic circular dichroism (ECD) spectra, as well as the two-photon absorption circular-linear dichroism measurements of three different chiral azo derivatives in dimethylsulfoxide solution. Using potential energy surfaces and frontier orbital analysis, we established the most stable conformation for each molecule and elucidated their different electronic transitions. Our theoretical calculations allowed us to unambiguously identify the spectral position of such transitions and correlate them with the spectral profiles observed in the two-photon absorption spectra. To further elucidate the characteris…