0000000000922023
AUTHOR
Sheng-hong Li
Abyssomicin E, a highly functionalized polycyclic metabolite from Streptomyces species.
Abyssomicin E (1), a new polycyclic metabolite with a C19 skeleton, was isolated from Streptomyces sp. (HKI0381). Its chemical structure was determined by comprehensive NMR and MS spectroscopic analyses. For the first time in this recently discovered class of compounds, the absolute stereochemistry was directly established by subsequent single-crystal X-ray diffraction study using anomalous dispersion with copper radiation.
CCDC 654035: Experimental Crystal Structure Determination
Related Article: Xue-Mei Niu, Sheng-Hong Li, Helmar Gorls, D.Schollmeyer, M.Hilliger, S.Grabley, I.Sattler|2007|Org.Lett.|9|2437|doi:10.1021/ol0705999