Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks.
A series of multifunctional 2D frameworks prepared with Dy(iii) and the bromanilato ligand, formulated as: [Dy2(C6O4Br2)3(G)n]·nG with G = H2O, dimethylformamide (dmf) and dimethylsulfoxide (dmso), can exchange the coordinated and non-coordinated solvent molecules (G) in a reversible way. These multifunctional frameworks show field induced slow relaxation of the magnetization and luminescence that can be easily and reversibly modified by solvent exchange.
CCDC 2005220: Experimental Crystal Structure Determination
Related Article: Samia Benmansour, Antonio Hernández-Paredes, Arpan Mondal, Gustavo López Martínez, Josep Canet-Ferrer, Sanjit Konar, Carlos J. Gómez-García|2020|Chem.Commun.|56|9862|doi:10.1039/D0CC03964K
CCDC 1565283: Experimental Crystal Structure Determination
Related Article: Samia Benmansour, Antonio Hernández-Paredes, Arpan Mondal, Gustavo López Martínez, Josep Canet-Ferrer, Sanjit Konar, Carlos J. Gómez-García|2020|Chem.Commun.|56|9862|doi:10.1039/D0CC03964K