6533b852fe1ef96bd12ab6ba

RESEARCH PRODUCT

Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks.

Samia BenmansourCarlos J. Gómez-garcíaJosep Canet-ferrerArpan MondalSanjit KonarGustavo López MartínezAntonio Hernández-paredes

subject

Materials scienceLigandRelaxation (NMR)Metals and AlloysGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventMagnetizationchemistry.chemical_compoundchemistryMaterials ChemistryCeramics and CompositesPhysical chemistryMoleculeDimethylformamideLuminescence

description

A series of multifunctional 2D frameworks prepared with Dy(iii) and the bromanilato ligand, formulated as: [Dy2(C6O4Br2)3(G)n]·nG with G = H2O, dimethylformamide (dmf) and dimethylsulfoxide (dmso), can exchange the coordinated and non-coordinated solvent molecules (G) in a reversible way. These multifunctional frameworks show field induced slow relaxation of the magnetization and luminescence that can be easily and reversibly modified by solvent exchange.

yearjournalcountryeditionlanguage
2020-08-26Chemical communications (Cambridge, England)
10.1039/d0cc03964khttps://pubmed.ncbi.nlm.nih.gov/32840511