0000000000931457
AUTHOR
Maja Zakrzyk
Hydrogen bond-mediated conjugates involving lanthanide diphthalocyanines and trifluoroacetic acid (Lnpc2@TFA): Structure, photoactivity, and stability
The interaction between lanthanide diphthalocyanine complexes, LnPc2 (Ln = Nd, Sm, Eu, Gd, Yb, Lu
Metallophthalocyanines as optical active dopants in borate glass
Abstract B2O3 – phthalocyanine composites (B2O3@MPc) were synthesized at 410 °C by sintering boron trioxide doped with base metal-free phthalocyanine (H2Pc) and/or its complexes of Mg, Zn, Gd (Pc = C32H16N8, phthalocyanine ligand, M = metal ion). The glassy products were characterized by scanning electron microscopy (SEM, EDS) and diffuse reflectance spectroscopy (DRS) which confirmed the incorporation of the respective phthalocyanines into the amorphous borate matrix. FTIR results suggested a possible impact of the phthalocyanine dopants on the final solid structure of the glassy matrix. The UV-excited composites emitted a pronounced blue phosphorescence featured by a two-step quenching pr…