0000000000932505
AUTHOR
Minna Sarkkinen
Sulphate removal over barium-modified blast-furnace-slag geopolymer
Blast-furnace slag and metakaolin were geopolymerised, modified with barium or treated with a combination of these methods in order to obtain an efficient SO4(2-) sorbent for mine water treatment. Of prepared materials, barium-modified blast-furnace slag geopolymer (Ba-BFS-GP) exhibited the highest SO4(2-) maximum sorption capacity (up to 119mgg(-1)) and it compared also favourably to materials reported in the literature. Therefore, Ba-BFS-GP was selected for further studies and the factors affecting to the sorption efficiency were assessed. Several isotherms were applied to describe the experimental results of Ba-BFS-GP and the Sips model showed the best fit. Kinetic studies showed that th…
Sulphate removal over barium-modified blast-furnace-slag geopolymer
Blast-furnace slag and metakaolin were geopolymerised, modified with barium or treated with a combination of these methods in order to obtain an efficient SO42− sorbent for mine water treatment. Of prepared materials, barium-modified blast-furnace slag geopolymer (Ba-BFS-GP) exhibited the highest SO42− maximum sorption capacity (up to 119 mg g−1) and it compared also favourably to materials reported in the literature. Therefore, Ba-BFS-GP was selected for further studies and the factors affecting to the sorption efficiency were assessed. Several isotherms were applied to describe the experimental results of Ba-BFS-GP and the Sips model showed the best fit. Kinetic studies showed that the so…
Metakaolin geopolymer characterization and application for ammonium removal from model solutions and landfill leachate
Abstract Geopolymers are aluminosilicate compounds that are amorphous analogues of zeolites, and thus possess similar cation-exchange properties. Geopolymers have been successfully applied to remove toxic metals and organic dyes from aqueous solutions. In this study, geopolymer was synthesized from metakaolin and applied to remove ammonium (NH 4 + ) from model solutions and landfill leachate. Geopolymerization increased the ammonium removal capacity, surface area and average pore width and changed the chemical structure of metakaolin. The maximum NH 4 + removal capacity of the geopolymer was 21.07 mg g − 1 which was 46% higher than the capacity of the reference clinoptilolite–heulandite zeo…