0000000000933387
AUTHOR
Ilga Kokorite
Impact of catchment properties on aquatic chemistry in the rivers of Latvia
The relationships between land use characteristics and aquatic chemistry (nutrient concentrations, major inorganic ions and indicators of organic matter concentrations) were analyzed to determine factors controlling the runoff of dissolved substances, spatial variability of water chemical composition and possible impacts of pollution sources in Latvia. Groups of factors were found to determine the variability of nutrient, organic matter and major inorganic ions concentrations. Bedrock geology and weathering of soil minerals affect the concentrations of inorganic ions, but the nature of the relationships between nutrient concentrations and those of land use are good indicators of human impac…
In Situ Ammonium Profiling Using Solid-Contact Ion-Selective Electrodes in Eutrophic Lakes
A promising profiling setup for in situ measurements in lakes with potentiometric solid-contact ion-selective electrodes (SC-ISEs) and a data processing method for sensor calibration and drift correction are presented. The profiling setup consists of a logging system, which is equipped with a syringe sampler and sensors for the measurement of standard parameters including temperature, conductivity, oxygen and photosynthetically active radiation (PAR). The setup was expanded with SC-ISEs in galvanically separated amplifiers. The potential for high-resolution profiling is investigated by deploying the setup in the eutrophic Lake Rotsee (Lucerne, Switzerland), using two different designs of am…
How to Assess the Ecological Status of Highly Humic Lakes? Development of a New Method Based on Benthic Invertebrates
Highly humic lakes are typical for the boreal zone. These unique ecosystems are characterised as relatively undisturbed habitats with brown water, high acidity, low nutrient content and lack of macrophytes. Current lake assessment methods are not appropriate for ecological assessment of highly humic lakes because of their unique properties and differing human pressures acting on these ecosystems. This study proposes a new approach suitable for the ecological status assessment of highly humic lakes impacted by hydrological modifications. Altogether, 52 macroinvertebrate samples from 15 raised bog lakes were used to develop the method. The studied lakes are located in the raised bogs at the c…
Natural organic matter export from boreal catchments (the Salaca River basin, Latvia) and its influencing factors
A noteworthy increase in the organic matter concentration and export, as well as water colour, in the catchments of the Salaca River has been observed during the last decades. This study investigates factors behind this increase: the impact of climate, land use and human loading changes on the concentrations and export of the organic matter in the Salaca River/Lake Burtnieks catchments. Proportion of wetlands in the river basin, type of land use, and runoff regime can be considered as the main factors influencing the organic carbon loadings. Despite a steady overall tendency of increase, considerable oscillations of organic matter loadings influenced by the changes in the river discharge re…
Widespread Increases in Iron Concentration in European and North American Freshwaters
Recent reports of increasing iron (Fe) concentrations in freshwaters are of concern, given the fundamental role of Fe in biogeochemical processes. Still, little is known about the frequency and geographical distribution of Fe trends or about the underlying drivers. We analyzed temporal trends of Fe concentrations across 340 water bodies distributed over 10 countries in northern Europe and North America in order to gain a clearer understanding of where, to what extent, and why Fe concentrations are on the rise. We found that Fe concentrations have significantly increased in 28% of sites, and decreased in 4%, with most positive trends located in northern Europe. Regions with rising Fe concent…
Widespread diminishing anthropogenic effects on calcium in freshwaters
Calcium (Ca) is an essential element for almost all living organisms. Here, we examined global variation and controls of freshwater Ca concentrations, using 440 599 water samples from 43 184 inland water sites in 57 countries. We found that the global median Ca concentration was 4.0 mg L−1 with 20.7% of the water samples showing Ca concentrations ≤ 1.5 mg L−1 , a threshold considered critical for the survival of many Ca-demanding organisms. Spatially, freshwater Ca concentrations were strongly and proportionally linked to carbonate alkalinity, with the highest Ca and carbonate alkalinity in waters with a pH around 8.0 and decreasing in concentrations towards lower pH. However, on a temporal…
Spectrofluorimetric study of dissolved organic matter in River Salaca (Latvia) basin waters
Dissolved organic matter (DOM) in surface waters influences mineral weathering, nutrient cycling, aggregation of particulate matter and photochemical reactions in waters and aquatic communities. In this study, the effectiveness of UV and fluorescence measurements in distinguishing the origin of DOM and processes within the river basin were analyzed using the River Salaca basin as an example. The basin of River Salaca is characterized by low anthropogenic pressure, however, the water color during the last few decades has increased (an effect known as brownification). As tools to study the composition of dissolved organic substances in waters of the River Salaca and its tributaries the use of…
Heavy metals in rivers of Latvia☆
Abstract Total heavy metal concentrations in waters and sediments (HNO 3 digestible Pb, Cu, Co, Ni, Mn, Zn) and their speciation forms in sediments (exchangeable, carbonate bound, iron–manganese oxide bound, organic matter bound and residual) in major and common small watercourses (31 sampling stations) along their flow in Latvia were determined. The metal loads entering the Baltic Sea from Latvia were calculated. Increased metal concentrations were found only in lower reaches of the largest rivers and locally around known industrial pollution sources. Differences in metal concentrations and loads in rivers from different regions of Latvia were related to natural geochemical processes. Meta…
Water quality in cutaway peatland lakes in Seda mire, Latvia
Remediation of industrially-milled peatland is an important task in the sustainable management of natural resources. Several approaches for wetland restoration, depending on local climatic and hydrological conditions, topography, physico-chemical properties of peat, as well as peat mining techniques, have been developed worldwide. However, most of the restoration activities include regulation of hydrological regime and surface topography in order to reintroduce typical bog vegetation, especially, Sphagnum cover, and to restore the peatland’s ecosystem close to its original conditions (Gorham and Rochefort, 2003; Farrell and Doyle, 2003; Lamers et al., 2002). In many countries, a significant…
Trends in nutrient concentrations in Latvian rivers and the response to the dramatic change in agriculture
In recent years, the use of fertilisers in the Baltic countries (Estonia, Latvia, and Lithuania) has decreased at an unprecedented rate. The import of mineral fertilisers and feed stuff became almost non-existent, and extensive slaughtering of livestock reduced the amount of manure. In Latvia, the purchase of mineral fertilisers decreased by a factor of 15 between 1987 and 1996 and the number of livestock decreased with a factor of almost 4 during the same time period. Such abrupt and comprehensive changes in land use have never before occurred in the history of modern European agriculture. Here, the impact that this dramatic reduction has had on concentrations of nutrients in Latvian river…
Data from: Widespread increases in iron concentration in European and North American freshwaters
Recent reports of increasing iron (Fe) concentrations in freshwaters are of concern, given the fundamental role of Fe in biogeochemical processes. Still, little is known about the frequency and geographical distribution of Fe trends, or about the underlying drivers. We analyzed temporal trends of Fe concentrations across 340 water bodies distributed over 10 countries in northern Europe and North America in order to gain a clearer understanding of where, to what extent, and why Fe concentrations are on the rise. We found that Fe concentrations have significantly increased in 28% of sites, and decreased in 4%, with most positive trends located in northern Europe. Regions with rising Fe concen…