0000000000940708
AUTHOR
Antony Lapprand
showing 43 related works from this author
Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size a…
2014
Bis(phenylthio)methane (L1) reacts with CuI to yield the 1D-coordination polymer [{Cu4(μ3-I)4}(μ-L1)2]n (1) bearing cubane Cu4I4 clusters as connecting nodes. The crystal structures at 115, 155, 195, and 235 K provided evidence for a phase transition changing from the monoclinic space group C2/c to P21/c. The self-assembly process of CuI with bis(p-tolylthio)methane (L2), bis(4-methoxyphenylthio)methane (L3), and bis(4-bromo-phenylthio)methane (L4) affords the 1D-coordination polymers [{Cu4(μ3-I)4}(μ-Lx)2]n (x = 2, 3, or 4). Compounds 2 and 4 are isostructural with C2/c low temperature polymorph of 1, whereas the inversion centers and 2-fold axes are lost in 3 (space group Cc). The use of b…
Luminescent P-Chirogenic Copper Clusters
2013
P-chirogenic clusters of the cubanes [Cu4I4L4] (L = chiral phosphine) were prepared from (+)- and (-)-ephedrine with L = (S)- or (R)-(R)(Ph)(i-Pr)P (with R = CH3 (seven steps) or C17H35 (10 steps)) with e.e. up to 96%. The X-ray structure of [Cu4I4((R)-(CH3)(Ph)(i-Pr)P)4] confirmed the cubane structure with average Cu···Cu and Cu···I distances of 2.954 and 2.696 Å, respectively. The cubane structure of the corresponding [Cu4I4((S)-(CH3)(Ph)(i-Pr)P)4] was established by the comparison of the X-ray powder diffraction patterns, and the opposite optical activity of the (S)- and (R)-ligand-containing clusters was confirmed by circular dichroism spectroscopy. Small-angle X-ray scattering patterns…
Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect
2013
A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
Organometallic Oligomers Based on Bis(arylacetylide)bis(P-chirogenic phosphine)platinum(II) Complexes: Synthesis and Photonic Properties
2013
A series of P-chirogenic oligomers of the type (-C≡C-aryl-C≡C-PtL2-)n [L = (R)- and (S)-P(Ph)(iPr)(C17H35); aryl = 1,4-benzene, 2,1,3-benzothiadiazole] along the corresponding achiral analogues (L = PBu3) and model complexes PhC≡CPtL2C≡CPh were prepared from the ephedrine strategy and were fully characterized [(1)H, (31)P NMR; IR; small-angle X-ray scattering (SAXS); gel permeation chromatography (GPC); thermal gravimetric analysis (TGA); circular dichroism, UV-vis, and luminescence spectroscopy; photophysics, and degree of anisotropy measurements]. From the CD measurements, the chiral environment of the phosphine ligands is modestly felt by the aryl moieties. Concurrently, the TGA shows th…
Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu I S and Cu I S Clusters to Luminescent Copper(I) Coordination Pol…
2015
The 1D coordination polymer (CP) [(Me2S)3{Cu2(μ-I)2}]n (1) is formed when CuI reacts with SMe2 in n-heptane, whereas in acetonitrile (MeCN), the reaction forms exclusively the 2D CP [(Me2S)3{Cu4(μ-I)4}]n (2) containing “flower-basket” Cu4I4 units. The reaction product of CuI with MeSEt is also solvent-dependent, where the 1D polymer [(MeSEt)2{Cu4(μ3-I)2(μ2-I)2}(MeCN)2]n (3) containing “stepped-cubane” Cu4I4 units is isolated in MeCN. In contrast, the reaction in n-heptane affords the 1D CP [(MeSEt)3{Cu4(μ3-I)4}]n (4) containing “closed-cubane” Cu4I4 clusters. The reaction of MeSPr with CuI provides the structurally related 1D CP [(MeSPr)3{Cu4(μ3-I)4}]n (5), for which the X-ray structure has…
CCDC 1047405: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047403: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047398: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974338: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047410: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974340: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047408: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974327: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047402: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047394: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974334: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 974333: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047411: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 947670: Experimental Crystal Structure Determination
2013
Related Article: Antony Lapprand, Antoine Bonnot, Michael Knorr, Youann Rousselin, Marek M. Kubicki, Daniel Fortin, Pierre D. Harvey|2013|Chem.Commun.|49|8848|doi:10.1039/C3CC45284K
CCDC 1047401: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1424523: Experimental Crystal Structure Determination
2015
Related Article: Antony Lapprand, Mathieu Dutartre, Naïma Khiri, Etienne Levert, Daniel Fortin, Yoann Rousselin, Armand Soldera, Sylvain Jugé and Pierre D. Harvey|2013|Inorg.Chem.|52|7958|doi:10.1021/ic400498j
CCDC 1047396: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974326: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 974341: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 974324: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047399: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974325: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047412: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047404: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974328: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047409: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047406: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047407: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974336: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 974335: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047400: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974337: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 974329: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 1047395: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 974339: Experimental Crystal Structure Determination
2014
Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z
CCDC 947669: Experimental Crystal Structure Determination
2013
Related Article: Antony Lapprand, Antoine Bonnot, Michael Knorr, Youann Rousselin, Marek M. Kubicki, Daniel Fortin, Pierre D. Harvey|2013|Chem.Commun.|49|8848|doi:10.1039/C3CC45284K
CCDC 1047413: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047397: Experimental Crystal Structure Determination
2015
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327