6533b85cfe1ef96bd12bc90b
RESEARCH PRODUCT
Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect
Daniel FortinPierre D. HarveyMarek M. KubickiAntoine BonnotMichael KnorrYoann RousselinAntony LapprandAntony Lapprandsubject
BromidesModels MolecularPolymersCoordination polymerInorganic chemistryHalide010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundHalogensPolymer chemistryMaterials ChemistryCluster (physics)ZeoliteComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationLuminescent Agents010405 organic chemistryMetals and AlloysGeneral ChemistryPolymer3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryVoid spaceZeolitesCeramics and CompositesLuminescenceCopperdescription
A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
year | journal | country | edition | language |
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2013-08-21 | Chemical Communications |