0000000001064294
AUTHOR
Antoine Bonnot
Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu I S and Cu I S Clusters to Luminescent Copper(I) Coordination Polymers
The 1D coordination polymer (CP) [(Me2S)3{Cu2(μ-I)2}]n (1) is formed when CuI reacts with SMe2 in n-heptane, whereas in acetonitrile (MeCN), the reaction forms exclusively the 2D CP [(Me2S)3{Cu4(μ-I)4}]n (2) containing “flower-basket” Cu4I4 units. The reaction product of CuI with MeSEt is also solvent-dependent, where the 1D polymer [(MeSEt)2{Cu4(μ3-I)2(μ2-I)2}(MeCN)2]n (3) containing “stepped-cubane” Cu4I4 units is isolated in MeCN. In contrast, the reaction in n-heptane affords the 1D CP [(MeSEt)3{Cu4(μ3-I)4}]n (4) containing “closed-cubane” Cu4I4 clusters. The reaction of MeSPr with CuI provides the structurally related 1D CP [(MeSPr)3{Cu4(μ3-I)4}]n (5), for which the X-ray structure has…
Antenna effects in truxene-bridged BODIPY triarylzinc(ii)porphyrin dyads: evidence for a dual Dexter–Förster mechanism
The antenna process from an energy donor (BODIPY; 4′,4′-difluoro-1′,3′,5′,7′-tetramethyl-4′-bora-3a′,4a′-diaza-s-indacene) in its singlet state to two acceptors (two zinc(II) 5,15-p-tolyl-10-phenylporphyrin) bridged by a central truxene residue (5′,5′′,10′,10′′,15′,15′′-hexabutyltruxene), 5, has been analysed by means of comparison of the energy transfer rates with those of a structurally similar β-substituted BODIPY-(zinc(II) 5,10,15-p-tolyl-porphyrin), 6, where no conjugation is present between the donor and the two acceptors using the Forster resonance energy transfer (FRET) approximation. It is estimated that the energy transfer in 5 operates mostly via a Dexter mechanism (>99%), and th…
Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect
A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
1,4-Bis(arylthio)but-2-enes as Assembling Ligands for (Cu2X2)n (X = I, Br; n = 1, 2) Coordination Polymers: Aryl Substitution, Olefin Configuration, and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties
CuI reacts with E-PhS(CH2CH═CHCH2)SPh, L1, to afford the coordination polymer (CP) [Cu2I2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1a). The unprecedented square-grid network of 1 is built upon alternating two-dimensional (2D) layers with an ABAB sequence and contains rhomboid Cu2(μ2-I)2 clusters as secondary building units (SBUs). Notably, layer A, interconnected by bridging L1 ligands, contains exclusively dinuclear units with short Cu···Cu separations [2.6485(7) A; 115 K]. In contrast, layer B exhibits Cu···Cu distances of 2.8133(8) A. The same network is observed when CuBr reacts with L1. In the 2D network of [Cu2Br2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1b), isotype to 1a, one square-grid-type layer contain…
Slow and Fast Singlet Energy Transfers in BODIPY-gallium(III)corrole Dyads Linked by Flexible Chains
Red (no styryl), green (monostyryl), and blue (distyryl) BODIPY-gallium(III) (BODIPY = boron-dipyrromethene) corrole dyads have been prepared in high yields using click chemistry, and their photophysical properties are reported. An original and efficient control of the direction of the singlet energy transfers is reported, going either from BODIPY to the gallium-corrole units or from gallium-corroles to BODIPY, depending upon the nature of the substitution on BODIPY. In one case (green), both directions are possible. The mechanism for the energy transfers is interpreted by means of through-space Förster resonance energy transfer (FRET).
CCDC 1047405: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418779: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047403: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047398: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047410: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418785: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047408: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418780: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047402: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418767: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418763: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047394: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418781: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418772: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418782: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418770: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418765: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047411: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 947670: Experimental Crystal Structure Determination
Related Article: Antony Lapprand, Antoine Bonnot, Michael Knorr, Youann Rousselin, Marek M. Kubicki, Daniel Fortin, Pierre D. Harvey|2013|Chem.Commun.|49|8848|doi:10.1039/C3CC45284K
CCDC 1047401: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418776: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418784: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047396: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047399: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418769: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418774: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418783: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418771: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047412: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047404: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047409: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047406: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047407: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418766: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418764: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418775: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047400: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1418762: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1431598: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418773: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1418768: Experimental Crystal Structure Determination
Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360
CCDC 1047395: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 947669: Experimental Crystal Structure Determination
Related Article: Antony Lapprand, Antoine Bonnot, Michael Knorr, Youann Rousselin, Marek M. Kubicki, Daniel Fortin, Pierre D. Harvey|2013|Chem.Commun.|49|8848|doi:10.1039/C3CC45284K
CCDC 1047413: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327
CCDC 1047397: Experimental Crystal Structure Determination
Related Article: Michael Knorr, Abderrahim Khatyr, Antony Lapprand, Antoine Bonnot, Carsten Strohmann, Marek M. Kubicki, Yoann Rousselin, Pierre D. Harvey|2015|Inorg.Chem.|54|4076|doi:10.1021/acs.inorgchem.5b00327