0000000000049178

AUTHOR

Michael Knorr

0000-0002-5647-8084

showing 105 related works from this author

Regioselective Synthesis of Mono- and Dispiropyrazoline Derivatives via 1,3-dipolar Cycloaddition with Nitrilimines

2016

The 1,3-dipolar cycloaddition reaction of (E,E)-1,3-bis(arylidene)indan-2-one with diarylnitrilimines, generated in situ via dehydrohalogenation of the corresponding hydrazonoyl chlorides , affords predominantly monospiropyrazolines and as a mixture of diastereoisomers. Also dispiropyrazolines are formed in moderate yields. The structure and stereochemistry of cycloadducts were confirmed by 1H and 13C-NMR spectroscopy, elemental analyses data, and single-crystal X-ray diffraction studies of and .

010405 organic chemistryChemistryOrganic ChemistryDiastereomerRegioselectivity010402 general chemistry01 natural sciencesMedicinal chemistryCycloaddition0104 chemical sciences13-Dipolar cycloadditionDehydrohalogenationOrganic chemistrySpectroscopyJournal of Heterocyclic Chemistry
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Synthesis of highly substituted spiropyrrolidines via 1, 3-dipolar cycloaddition reaction of N-metalated azomethine ylides. A new access to spiropyrr…

2015

1,3-dipolar cycloaddition of (E)-arylidene-(2H)-indanones 1 (Ar = Ph, p-MeC6H4, p-MeOC6H4, p-ClC6H4) and (E)-2-arylidene-(2H)-tetralones 2 (Ar = Ph, p-MeC6H4, p-MeOC6H4, p-ClC6H4) to N-metalated azomethine ylides 3 generated from methyl N-arylideneglycinate in the presence of silver acetate produces in good yields novel spiro[3,5-(diaryl)-2-carbomethoxypyrrolidine-4:2’-indanones] 4 and spiro[3,5-(diaryl)-2-carbomethoxypyrrolidine-4:2’-tetral-1-ones] 5. The cycloaddition proceeds in regio- and stereoselective manner (100%) at room temperature to afford respectively the syn-endo cycloadducts 4 and 5 via metallo-azomethine ylides. The regio- and stereochemistry of the spiranic adducts has been…

lcsh:Chemistrylcsh:QD1-999010405 organic chemistry[CHIM] Chemical Sciences[CHIM]Chemical SciencesGeneral Chemistry010402 general chemistry01 natural sciencesComputingMilieux_MISCELLANEOUS0104 chemical sciences
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Reactivity of CuI and CuBr toward Et2S: a reinvestigation on the self-assembly of luminescent copper(I) coordination polymers.

2010

CuI reacts with SEt(2) in hexane to afford the known strongly luminescent 1D coordination polymer [(Et(2)S)(3){Cu(4)(mu(3)-I)(4)}](n) (1). Its X-ray structure has been redetermined at 115, 235, and 275 K in order to address the behavior of the cluster-centered emission and is built upon Cu(4)(mu(3)-I)(4) cubane-like clusters as secondary building units (SBUs), which are interconnected via bridging SEt(2) ligands. However, we could not reproduce the preparation of a coordination polymer with composition [(Et(2)S)(3){Cu(4)(mu(3)-Br)(4)}](n) as reported in Inorg. Chem. 1975, 14, 1667. In contrast, the autoassembly reaction of SEt(2) with CuBr results in the formation of a novel 1D coordination…

chemistry.chemical_classificationCoordination polymerInorganic chemistrychemistry.chemical_elementBridging ligandPolymerCrystal structureCopperInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryDensity functional theorySBusPhysical and Theoretical ChemistryLuminescenceInorganic chemistry
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Effect of t-BuS vs. n-BuS on the topology, Cu⋯Cu distances and luminescence properties of 2D Cu4I4/RS(CH2)4SR metal–organic frameworks

2011

CuI reacts with RS(CH2)4SR (R = n-Bu (L1); t-Bu (L2)) to afford the 2D coordination polymers [Cu4I4{μ-RS(CH2)4SR}2]n (R = n-Bu (1); t-Bu (2)). Their grid networks exhibit nodal Cu4(μ3-I)4 clusters interconnected by dithioethers with mean Cu⋯Cu distances of 2.7265(10) and 2.911(2) A for 1 and 2, respectively. This difference translates in a blue shift of the solid state emission bands and a decrease in emission lifetimes when trading R = n-Bu to the bulky t-Bu.

chemistry.chemical_classificationCrystallographychemistryComputational chemistryMaterials ChemistrySolid-stateMetal-organic frameworkGeneral ChemistryPolymerLuminescenceCatalysisTopology (chemistry)BlueshiftNew Journal of Chemistry
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Bis(4-methylthio)phenylthiomethane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topolo…

2016

International audience; The novel 1D coordination polymer (CP) [{Cu(mu(2)-Br)(2)Cu}(mu-L2)(2)] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1: 2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(mu(2)-Br)(2)Cu}(mu-L1)(2)] CP1 obtained by reaction of the tetrakisthioether p-MeOC6H4SCH2SC6H4OMe-p (L1) with CuBr, the two independent extended 1D ribbons contain bent Cu(mu(2)-Br)(2)Cu units of the butterfly-type with short Cu center dot center dot center dot Cu separations of 2.679(1) and 2.613(1) angstrom. In contrast to the common planar rhomboid Cu(mu(2)-Br)(2)Cu cluster, this butterfly-shaped geometry of the core …

QT-AIMLuminescenceCoordination polymerStereochemistryCoordination number[ PHYS.ASTR ] Physics [physics]/Astrophysics [astro-ph]StackingCrystal structure[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciences[ CHIM ] Chemical Sciencesdinuclear copper(i) complexesInorganic Chemistrychemistry.chemical_compoundelectron-densityThioetheraryl substitutionMaterials Chemistry[CHIM]Chemical Sciencescluster-sizePhysical and Theoretical Chemistrytetrathioether complexesComputingMilieux_MISCELLANEOUSThioether complexesluminescence properties010405 organic chemistrypi-pi stackingAtoms in moleculescu-i interaction[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryMercury0104 chemical sciencesCoordination polymersCrystallographychemistryCovalent bondextended 1dStoichiometryCoppermetal-complexes
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Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size a…

2014

Bis(phenylthio)methane (L1) reacts with CuI to yield the 1D-coordination polymer [{Cu4(μ3-I)4}(μ-L1)2]n (1) bearing cubane Cu4I4 clusters as connecting nodes. The crystal structures at 115, 155, 195, and 235 K provided evidence for a phase transition changing from the monoclinic space group C2/c to P21/c. The self-assembly process of CuI with bis(p-tolylthio)methane (L2), bis(4-methoxyphenylthio)methane (L3), and bis(4-bromo-phenylthio)methane (L4) affords the 1D-coordination polymers [{Cu4(μ3-I)4}(μ-Lx)2]n (x = 2, 3, or 4). Compounds 2 and 4 are isostructural with C2/c low temperature polymorph of 1, whereas the inversion centers and 2-fold axes are lost in 3 (space group Cc). The use of b…

Steric effectsArylGeneral ChemistryCrystal structureCondensed Matter PhysicsPhotochemistryMethanechemistry.chemical_compoundCrystallographychemistryCubaneRibbon[CHIM]Chemical SciencesGeneral Materials ScienceIsostructuralComputingMilieux_MISCELLANEOUSMonoclinic crystal system
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Synthesis of Isoxazole and 1,2,3-Triazole Isoindole Derivatives via Silver- and Copper-Catalyzed 1,3-Dipolar Cycloaddition Reaction.

2016

International audience; The CuI-or Ag 2 CO 3-catalyzed [3+2] cycloaddition of propargyl-substituted dihydroisoindolin-1-one (3) with arylnitrile oxides 1a-d (Ar = Ph, p-MeC 6 H 4 , p-MeOC 6 H 4 , p-ClC 6 H 4) produces in good yields novel 3,5-disubstituted isoxazoles 4 of the ethyl-2-benzyl-3-oxo-1-((3-arylisoxazol-5yl)methyl)-2,3-dihydro-1H-isoindole-1-carboxylate type. With aryl azides 2a-d (Ar = Ph, p-MeC 6 H 4 , p-OMeC 6 H 4 , p-ClC 6 H 4), a series of 1,4-disubstituted 1,2,3-triazoles 6 (ethyl-2-benzyl-3-oxo-1-((1-aryl-1H-1,2,3-triazol-4-yl)methyl)-2,3-dihydro-1H-isoindole-1-carboxylates) was obtained. The reactions proceed in a regioselective manner affording exclusively racemic adduc…

123-TriazoleMagnetic Resonance SpectroscopySilverSpectrophotometry Infrared12Pharmaceutical Science[3+2] dipolar cycloaddition; arylnitrile oxides; arylazides; isoxazole; 123-triazolesarylazidesIsoindoles010402 general chemistryCrystallography X-Ray01 natural sciencesMedicinal chemistryCatalysisArticleAnalytical Chemistrylcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryDrug DiscoveryOrganic chemistryPhysical and Theoretical ChemistryIsoxazoleCycloaddition Reaction010405 organic chemistryArylOrganic ChemistryisoxazoleRegioselectivityIsoxazolesarylnitrile oxidesTriazolesCycloaddition0104 chemical scienceschemistryChemistry (miscellaneous)13-Dipolar cycloaddition[3+2] dipolar cycloadditionMolecular Medicine123-triazoles3-triazolesIsoindoleSelectivity[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph]CopperMolecules (Basel, Switzerland)
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Reinvestigation of the Pd-catalysed bis(silylation) of alkynes with 1,1,2,2-tetramethyl-1,2-bis(phenylthiomethyl)disilane: Unexpected formation of th…

2013

International audience; The bis(silylated) alkenes Z-(PhSCH2)Me2SiC(H)=C(Fc)SiMe2(CH2SPh) (2) and Z-(PhSCH2)Me2SiC(H)=C(bipheny)SiMe2(CH2SPh) (3) have been prepared by Pd-catalysed double silylation of ethynylferrocene and 4-ethynyl-1,1'-biphenyl in the presence of 1,1,2,2-tetramethyl-1,2-bis(phenylthiomethyl)disilane (1). A reinvestigation on the interaction of 1 with [PdCl2(PhCN)2] in technical-grade CH2Cl2 as solvent revealed competition between reduction to elemental palladium (due to oxidative addition of the Si-Si bond across Pd(II) and subsequent reductive elimination) and formation of an unusual eight-membered chelate complex cis-[PdCl2{(PhSCH2SiMe2)2O}] (4), which is fluxional in s…

SilylationStereochemistryEthynylferrocene[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciencesBiochemistryMedicinal chemistryDFTReductive eliminationInorganic Chemistrychemistry.chemical_compound[ CHIM.CRIS ] Chemical Sciences/Cristallography[ CHIM.ORGA ] Chemical Sciences/Organic chemistryDisilaneMaterials Chemistry[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryConformational isomerismComputingMilieux_MISCELLANEOUSThioether complexesSiloxane010405 organic chemistryLigand[CHIM.ORGA]Chemical Sciences/Organic chemistryOrganic Chemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistry[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryDisiloxaneOxidative addition0104 chemical scienceschemistrySiloxaneDisilanePalladium
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Synthesis, crystallographic and electrochemical study of ethynyl[2.2]paracyclophane derived cobalt metallatetrahedranes

2012

Abstract A series of alkynyl cobalt complexes [Co2(μ-η2-HCC–PCP)(CO)6−nLn] [n = 0 (2); n = 2, L2 = dppa (3), dppm (4), dcpm (6), 2 P(OPh)3 (7)] and [Co2(CO)4L2]2(μ-η2:μ-η2-HCC–PCP–CCH)] (L2 = dppm (8), dcpm (9); (PCP = [2.2]paracyclophane) has been prepared and characterized. The molecular structures of 3 and 4, as well as that of [Co2(CO)4(μ-CO)2(μ2-dcpm)] (5), have been determined by X-ray diffraction. Electrochemical studies (Cyclic Voltammetry, Rotating Disk Electrode) and luminescence spectroscopy have been used to evaluate the extent of the electronic communication through the PCP motif using the “Co2C2” centres as a probe. No electronic coupling between the Co2(CO)n centres via the b…

chemistry.chemical_elementAlkyne[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryElectrochemistry01 natural sciencesBiochemistryInorganic ChemistryMaterials ChemistryluminescencealkyneElectronic communication[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryRotating disk electrodeSpectroscopyComputingMilieux_MISCELLANEOUSchemistry.chemical_classification010405 organic chemistryOrganic Chemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistry[ CHIM.INOR ] Chemical Sciences/Inorganic chemistrycobalt0104 chemical sciencesCrystallographychemistryelectrochemistryCyclic voltammetry[2.2]paracyclophaneLuminescenceCobalt
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Regio- and Stereoselective Synthesis of Spiropyrrolizidines and Piperazines through Azomethine Ylide Cycloaddition Reaction.

2015

A series of original spiropyrrolizidine derivatives has been prepared by a one-pot three-component [3 + 2] cycloaddition reaction of (E)-3-arylidene-1-phenyl-pyrrolidine-2,5-diones, l-proline, and the cyclic ketones 1H-indole-2,3-dione (isatin), indenoquinoxaline-11-one and acenaphthenequinone. We disclose an unprecedented isomerization of some spiroadducts leading to a new family of spirooxindolepyrrolizidines. Furthermore, these cycloadducts underwent retro-1,3-dipolar cycloaddition yielding unexpected regioisomers. Upon treatment of the dipolarophiles with in situ generated azomethine ylides from l-proline or acenaphthenequinone, formation of spiroadducts and unusual polycyclic fused pip…

IsatinThiosemicarbazonesStereochemistryAzomethine ylideStereoisomerism010402 general chemistry01 natural sciencesPiperazineschemistry.chemical_compoundX-Ray DiffractionStructural isomerSpiro CompoundsComputingMilieux_MISCELLANEOUSPyrrolizidine AlkaloidsCycloaddition Reaction010405 organic chemistryHydrogen bondIsatinOrganic ChemistryStereoisomerismCycloaddition0104 chemical sciencesKineticschemistryCyclizationQuantum TheoryStereoselectivity[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph]IsomerizationAzo CompoundsThe Journal of organic chemistry
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Formation of (σ‐Alkenyl)‐ and (μ‐Vinylidene)palladium and ‐platinum Complexes by Oxidative Addition of 4,4‐Dichloro‐1,1‐diphenyl‐2‐azabuta‐1,3‐diene …

2003

4,4-Dichloro-1,1-diphenyl-2-azabuta-1,3-diene (1) oxidatively adds to [Pd(PPh3)4] and [Pt(C2H4)(PPh3)2] giving rise to the σ-alkenyl complexes trans-[MCl{[C(Cl)=C(H)−N=CPh2]}(PPh3)2] (2a: M = Pd; 2b: M = Pt). When 1 is treated with [Pd(PPh3)4] in a 1:2 ratio in refluxing toluene, the dimetallic μ-vinylidene complex [(PPh3)ClPd{μ-[C=C(H)−N=CPh2]}PdCl(PPh3)2] (3) is formed. In this fluxional compound, a PPh3 ligands migrates in a reversible manner between the two Pd centers. Substitution of the PPh3 ligands of 3 by 2 equiv. of Ph2PCH2PPh2 affords the A-frame complex [ClPd(μ-dppm)2{μ-[C=C(H)−N=CPh2]}PdCl] (4). (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

Inorganic Chemistrychemistry.chemical_compoundchemistryDieneStereochemistryMoleculechemistry.chemical_elementPlatinumMedicinal chemistryTolueneOxidative additionPalladiumEuropean Journal of Inorganic Chemistry
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1,3-Dipolar cycloaddition of diaryldiazomethanes across N-ethoxy-carbonyl-N-(2,2,2-trichloroethylidene)amine and reactivity of the resulting 2-azabut…

2016

Abstract 1,3-dipolar cycloaddition of diaryldiazomethanes Ar2C N2 across Cl3C–CH N–CO2Et 1 yields Δ3-1,2,4-triazolines 2. Thermolysis of 2 leads, via transient azomethine ylides 3, to diaryldichloroazabutadienes [Ar(Ar')C N–CH CCl2] 4. Treatment of 4a (Ar = Ar' = C6H5) and 4c (Ar = Ar' = p-ClC6H4) with NaSR in DMF yields 2-azabutadienes [Ar2C N–C(H) C(SR)2] 5. In contrast, nucleophilic attack of NaStBu on 4 affords azadienic dithioethers [Ar2C N–C(StBu) C(H)(StBu)] (7a Ar = C6H5; 7b Ar' = p-ClC6H4). The reaction of 4a with NaSEt conducted in neat EtSH produces [Ph2C N–C(H)(SEt)–CCl2H] 8, which after dehydrochloration by NaOMe and subsequent addition of NaSEt is converted to [Ph2C N–C(SEt) C…

Chemistry(all)StereochemistryGeneral Chemical Engineering124-TriazolineCrystal structure010402 general chemistry01 natural sciencesMedicinal chemistrychemistry.chemical_compoundThioetherNucleophile[CHIM]Chemical SciencesReactivity (chemistry)ThioetherCycloadditionComputingMilieux_MISCELLANEOUS2-Azabutadienes010405 organic chemistryGeneral ChemistryCycloaddition0104 chemical sciences3. Good healthchemistry13-Dipolar cycloadditionAzomethine ylidesChemical Engineering(all)Alkoxy groupPiperidineCopperMacrocyclic complexComptes Rendus Chimie
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Electrochemical deposition of a luminescent alkoxysilyl-based fluorenone film exhibiting halide sensitivity

2016

International audience

Materials science010405 organic chemistryInorganic chemistryHalide010402 general chemistryPhotochemistryElectrochemistry01 natural sciencesSensitivity (explosives)0104 chemical sciencesElectronic Optical and Magnetic Materialschemistry.chemical_compoundFluorenonechemistry[CHIM]Chemical SciencesLuminescenceDeposition (law)ComputingMilieux_MISCELLANEOUS
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Mono- and di-nuclear 2,3-diazabutadiene and 2-azabutadiene complexes of Rhenium(I): Syntheses, luminescence spectra and X-ray structures

2008

Abstract Treatment of [Re(CO)3(THF)(μ-Br)]2 with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C C(H)–N CPh2] (1a) yields the di-nuclear benzophenone azine-bridged compound [(OC)3Re(μ-Ph2C N–N CPh2)(μ-Br)2Re(CO)3] (2a), albeit in low yield. Alternatively, compounds [(OC)3Re(μ-Ph2C N–N CPh2)(μ-X)2Re(CO)3] (2a,b) (X = Br, Cl) are obtained in high yields by direct reaction of [Re(CO)3(THF)(μ-Br)]2 or [Re(CO)5Cl] with benzophenone azine. Nucleophilic attack of NaSPh on 1a affords the 2-azabutadiene derivative [(PhS)(Cl)C C(H)–N CPh2] (1b), which upon reaction with [Re(CO)3(THF)(μ-Br)]2 forms the S,N-chelate complex fac-[(OC)3ReBr{(PhS)(Cl)C C(H)–N CPh2}] (3). The crystal structures of 1b, 2…

Stereochemistrychemistry.chemical_elementCrystal structureRheniumMedicinal chemistryInorganic ChemistryAzinechemistry.chemical_compoundchemistryNucleophileThioetherMaterials ChemistryBenzophenonePhysical and Theoretical ChemistryLuminescenceDerivative (chemistry)Inorganic Chemistry Communications
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4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene

2007

In the title compound, C29H25NS2, both the Cl atoms of the azadiene precursor 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-azabutadiene array. The azadiene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly π-conjugated with the azadiene core [dihedral angle 5.1 (2)°].

CrystallographyDiene010405 organic chemistryGeneral ChemistryDihedral angle010402 general chemistryCondensed Matter PhysicsBioinformaticsOrganic Papers01 natural sciencesMedicinal chemistry3. Good health0104 chemical scienceschemistry.chemical_compoundchemistryQD901-999General Materials ScienceVicinalActa Crystallographica Section E
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Reactivity of 4,4-Dichloro-1,1-diphenyl-2-azabutadiene Towards Alkoxides and Thiolates: Synthesis of Functionalised π-Conjugated 2-Azabutadienes and …

2006

Treatment of 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C=C(H)-N=CPh2] (1) with excess sodium isopropylthiolate or sodium thiophenolate in DMF yielded the 2-azabutadiene derivatives (RS)2C=C(H)–N=CPh2 (2) (2a R = iPr; 2b R = Ph). Nucleophilic attack of the sodium salt of ethyl thioglycolate on 1 afforded as the sole product the six-membered heterocyclic compound ethyl 2-ethoxycarbonylmethylthio-5,5-diphenyl-5,6-dihydro-4H-1,4-thiazine-6-carboxylate (5). The reaction is initiated by substitution of the two vinyl-bound chloro substituents to give {EtO(O=)CCH2S}2C=C(H)–N=CPh2 (2c) as intermediate. A mechanism that accounts for the subsequent cyclisation reaction is proposed. The 2-azabu…

chemistry.chemical_classificationStereochemistrySodiumOrganic Chemistrychemistry.chemical_elementRegioselectivityConjugated systemMedicinal chemistrychemistry.chemical_compoundNucleophilechemistryThiazineHeterocyclic compoundHSAB theoryReactivity (chemistry)Physical and Theoretical ChemistryEuropean Journal of Organic Chemistry
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Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu I S and Cu I S Clusters to Luminescent Copper(I) Coordination Pol…

2015

The 1D coordination polymer (CP) [(Me2S)3{Cu2(μ-I)2}]n (1) is formed when CuI reacts with SMe2 in n-heptane, whereas in acetonitrile (MeCN), the reaction forms exclusively the 2D CP [(Me2S)3{Cu4(μ-I)4}]n (2) containing “flower-basket” Cu4I4 units. The reaction product of CuI with MeSEt is also solvent-dependent, where the 1D polymer [(MeSEt)2{Cu4(μ3-I)2(μ2-I)2}(MeCN)2]n (3) containing “stepped-cubane” Cu4I4 units is isolated in MeCN. In contrast, the reaction in n-heptane affords the 1D CP [(MeSEt)3{Cu4(μ3-I)4}]n (4) containing “closed-cubane” Cu4I4 clusters. The reaction of MeSPr with CuI provides the structurally related 1D CP [(MeSPr)3{Cu4(μ3-I)4}]n (5), for which the X-ray structure has…

chemistry.chemical_classificationStereochemistryCoordination polymerchemistry.chemical_elementPolymerCopperReaction productInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryReactivity (chemistry)SBusPhysical and Theoretical ChemistryAcetonitrileLuminescence
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ChemInform Abstract: Regio- and Stereoselective Synthesis of Spiropyrrolizidines and Piperazines Through Azomethine Ylide Cycloaddition Reaction.

2016

A series of original spiropyrrolizidine derivatives has been prepared by a one-pot three-component [3 + 2] cycloaddition reaction of (E)-3-arylidene-1-phenyl-pyrrolidine-2,5-diones, l-proline, and the cyclic ketones 1H-indole-2,3-dione (isatin), indenoquinoxaline-11-one and acenaphthenequinone. We disclose an unprecedented isomerization of some spiroadducts leading to a new family of spirooxindolepyrrolizidines. Furthermore, these cycloadducts underwent retro-1,3-dipolar cycloaddition yielding unexpected regioisomers. Upon treatment of the dipolarophiles with in situ generated azomethine ylides from l-proline or acenaphthenequinone, formation of spiroadducts and unusual polycyclic fused pip…

chemistry.chemical_compoundHydrogen bondChemistryIsatinStructural isomerAzomethine ylideStereoselectivityGeneral MedicineMedicinal chemistryIsomerizationCycloadditionChemInform
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(2,2‐Dibromovinyl)ferrocene as a Building Block for the Assembly of Heterodinuclear Complexes – Preparation of an σ‐Alkenylpalladium Complex and Dime…

2007

The oxidative addition of (2,2-dibromovinyl)ferrocene [Br2C=C(H)–Fc] (1) to [Pd(PPh3)4] yields the heterodinuclear σ-alkenyl complex trans-[{Pd(Br)(PPh3)2}–C(Br)=C(H)–Fc] (2). Nucleophilic attack of sodium thiolates on 1 unexpectedly affords the vinyl thioether derivatives (Z)-[(RS)(H)C=C(H)–Fc] (4a: R = Ph; 4b: R = tBu; 4c: R = Et). Complexes 4a and 4c can also be prepared by addition of NaSR across the triple bond of Fc–C≡C–H (3). Addition of an excess of NaSR to 1 affords the dithioether derivatives (Z)-[(RS)(H)C=C(SR)–Fc] (5a: R = Ph; 5b: R = p-tolyl; 5c: R = Et). An addition/elimination sequence is suggested to account for this surprising result. The yield of 5c is very low due to a co…

Stereochemistrychemistry.chemical_elementRheniumMetathesisTriple bondMedicinal chemistryOxidative additionInorganic Chemistrychemistry.chemical_compoundFerrocenechemistryThioetherNucleophilePalladiumEuropean Journal of Inorganic Chemistry
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Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect

2013

A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.

BromidesModels MolecularPolymersCoordination polymerInorganic chemistryHalide010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundHalogensPolymer chemistryMaterials ChemistryCluster (physics)ZeoliteComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationLuminescent Agents010405 organic chemistryMetals and AlloysGeneral ChemistryPolymer3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryVoid spaceZeolitesCeramics and CompositesLuminescenceCopperChemical Communications
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Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

2015

The title compound belongs to the large family of heterodinuclear phosphide-bridged complexes. The Fe—Pt bond is of 2.7738 (4) Å and there is an unprecedented arrangement of the silyl ligand in a trans-position with respect to the metal–metal vector in the family of phosphide-bridged iron–platinum heterobimetallics.

crystal structuremetal–metal bondSilylationStereochemistrychemistry.chemical_elementCrystal structureMedicinal chemistryResearch Communicationslcsh:Chemistrychemistry.chemical_compoundphosphido bridges[CHIM]Chemical SciencesGeneral Materials Sciencediphenylmethylsilyl ligandComputingMilieux_MISCELLANEOUSdi­phenyl­methyl­silyl ligandLigandTricarbonGeneral ChemistryCondensed Matter Physics3. Good healthiron complexeslcsh:QD1-999chemistryheterobimetallicsPlatinumplatinum complexesActa Crystallographica Section E Crystallographic Communications
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Synthesis of μ-C2S44− Cobalt Complexes by Activation of the 1,3,4,6-tetrathiapentalene-2,5-dione, and Electrochemical Study of [(Cp*Co)2(μ-C2S4)]

2002

The bimetallic complex [Cp(*)Co)2(μ-C2S4)] in which the two metal centres are linked by an ethylenetetrathiolate C2S44− unit, was synthesized in high yield by oxidative addition of 1,3,4,6 tetrathiapentalene-2,5-dione to [Cp(*)Co(CO)2]. The X-ray crystal structure of the intermediate product Cp*Co(dmid) (dmid2− = 4,5-disulfanyl-1,3-dithiol-2-onate) is presented. The electrochemical behaviour of the [(Cp*Co)2(μ-C2S4)] complex was studied in detail in the oxidative range. This study has shown that the nature of the product obtained after oxidation depends on the presence of complexing agent in the solution. The mechanism has been elucidated in a CH2Cl2 solution in the presence of P(OMe)3. In …

ChemistryStereochemistrychemistry.chemical_elementCrystal structureElectrochemistryOxidative additionMedicinal chemistryInorganic ChemistryMetalvisual_artYield (chemistry)visual_art.visual_art_mediumMoleculeCobaltBimetallic stripEuropean Journal of Inorganic Chemistry
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1,3-Dipolar Cycloaddition Reactions of Indan-1-one Enamines across Arylnitrile Oxides Leading to Novel Cyclic Isoxazoline Derivatives

2013

Synthesis of a series of cyclic fused-isoxazolines has been accomplished by regioselective and diastereoselective 1,3-dipolar cycloaddition of 3-methylindan-1-one enamines (1a, 1b, 1c) and 3-phenylindan-1-one enamines (2a, 2b, 2c) to arylnitrile oxides (3d, 3e, 3f, 3g, 3h). The structure of the cycloadducts was elucidated by 1H and 13C NMR spectroscopy. The proposed regio- and stereochemistry of fused-compounds (4) and (5) has also been corroborated by two single-crystal X-ray diffraction studies carried out on 4-methyl-8b-morpholinyl-3-(p-tolyl)-4H-3a,8b-dihydroindeno[2,3-d]isoxazoline (4be) and 3-(p-anisyl)-4-phenyl-8b-pyrrolidinyl-4H-3a,8b-dihydroindeno[2,3-d]isoxazoline (5af) and by mea…

13c nmr spectroscopy010405 organic chemistryStereochemistryChemistryOrganic Chemistry13-Dipolar cycloadditionRegioselectivityDensity functional theory010402 general chemistry01 natural sciencesMedicinal chemistryCycloaddition0104 chemical sciencesJournal of Heterocyclic Chemistry
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1,4-Bis(arylthio)but-2-enes as Assembling Ligands for (Cu2X2)n (X = I, Br; n = 1, 2) Coordination Polymers: Aryl Substitution, Olefin Configuration, …

2016

CuI reacts with E-PhS(CH2CH═CHCH2)SPh, L1, to afford the coordination polymer (CP) [Cu2I2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1a). The unprecedented square-grid network of 1 is built upon alternating two-dimensional (2D) layers with an ABAB sequence and contains rhomboid Cu2(μ2-I)2 clusters as secondary building units (SBUs). Notably, layer A, interconnected by bridging L1 ligands, contains exclusively dinuclear units with short Cu···Cu separations [2.6485(7) A; 115 K]. In contrast, layer B exhibits Cu···Cu distances of 2.8133(8) A. The same network is observed when CuBr reacts with L1. In the 2D network of [Cu2Br2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1b), isotype to 1a, one square-grid-type layer contain…

chemistry.chemical_classificationOlefin fiber010405 organic chemistryCoordination polymerStereochemistryArylHalideGeneral ChemistryPolymer010402 general chemistryCondensed Matter Physics01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryGeneral Materials ScienceSBusLuminescenceCurse of dimensionalityCrystal Growth & Design
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Synthesis and reactivity of an 2-azabutadiene-based π-conjugated dithioether: Formation of a N,S-ligated molybdenum chelate complex and C,N,S-pincer …

2005

Abstract Nucleophilic attack of sodium isopropylthiolate on 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C C(H)–N CPh2}] (1) affords the 2-azabutadiene derivative [(i-PrS)2C C(H)–N CPh2] (2). Upon irradiation of Mo(CO)6 in THF in the presence of 2, the chelate complex cis-[(OC)4Mo{(i-PrS)2C C(H)–N CPh2}] (3) is obtained. Coordination on Mo occurs through the imine nitrogen and a thioether group. Polydentate dithioether 2 acts as N,C,S-pincer ligand after orthometallation reaction with Pd(II) or Pt(II). The molecular structures of 2 and (C,N,S)-[(i-PrS)2C C(H)–N C(Ph)C6H4)PtCl] (4b) have been determined by X-ray diffraction studies.

DenticityLigandStereochemistryIminechemistry.chemical_elementMedicinal chemistryPincer movementInorganic Chemistrychemistry.chemical_compoundNucleophilechemistryThioetherMaterials ChemistryReactivity (chemistry)Physical and Theoretical ChemistryPalladiumInorganic Chemistry Communications
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CCDC 1029334: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographymethyl 2'4'-bis(4-methylphenyl)-1-oxo-13-dihydrospiro[indene-23'-pyrrolidine]-5'-carboxylateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1029336: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal Structuremethyl 2'-(4-chlorophenyl)-4'-(4-methylphenyl)-1-oxo-34-dihydro-1H-spiro[naphthalene-23'-pyrrolidine]-5'-carboxylateCell ParametersExperimental 3D Coordinates
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CCDC 1405446: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1'-(4-fluorophenyl)-1''-phenyl-5'6'7'7a'-tetrahydro-1'H2''H5''H-dispiro[indole-33'-pyrrolizine-2'3''-pyrrolidine]-22''5''(1H)-trioneExperimental 3D Coordinates
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CCDC 1405448: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal System1'-(4-chlorophenyl)-1''-phenyl-5'6'7'7a'-tetrahydro-1'H2''H5''H-dispiro[indole-33'-pyrrolizine-2'3''-pyrrolidine]-22''5''(1H)-trioneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047405: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systemtetrakis(mu3-Iodo)-tetrakis(di-n-propyl sulfide)-tetra-copperCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418779: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-11'-(butane-14-diyldisulfanediyl)bis(4-methylbenzene))-bis(mu-iodo)-di-copper]Experimental 3D Coordinates
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CCDC 835277: Experimental Crystal Structure Determination

2015

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N-(12-bis(t-butylsulfanyl)vinyl)-11-bis(4-chlorophenyl)methanimineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047403: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographycatena-(tetrakis(mu3-Iodo)-(mu2-methyl n-propyl sulfide)-bis(methyl n-propyl sulfide)-tetra-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047398: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systembis(mu4-Iodo)-hexakis(mu3-iodo)-hexakis(di-isopropyl sulfide)-octa-copperCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974338: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographybis(mu2-Bromo)-tetrakis(bis(p-tolylthio)methane-S)-di-copperCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047410: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu3-Bromo)-tris(mu2-ethyl methyl sulfide)-tris(mu2-bromo)-(ethyl methyl sulfide)-tetra-copper)Experimental 3D Coordinates
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CCDC 974340: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-11'-(methylenedisulfanediyl)bis(3-methylbenzene))-bis(mu2-bromo)-di-copper]Experimental 3D Coordinates
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CCDC 1418785: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047408: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systemtetrakis(mu3-Iodo)-tetrakis(di-n-propyl sulfide)-tetra-copperCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 835276: Experimental Crystal Structure Determination

2015

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N-(12-bis(t-butylsulfanyl)vinyl)-11-diphenylmethanimineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418780: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal Systemcatena-[(mu-cis-1-methyl-4-((4-((4-methylphenyl)sulfanyl)but-2-en-1-yl)sulfanyl)benzene)-(mu-iodo)-copper(i)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974327: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu3-Iodo)-bis(mu2-bis(phenylthio)methane-SS')-tetra-copper)Experimental 3D Coordinates
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CCDC 1047402: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographycatena-(tetrakis(mu3-Iodo)-(mu2-methyl n-propyl sulfide)-bis(methyl n-propyl sulfide)-tetra-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418767: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]
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CCDC 1418763: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal Systemcatena-[bis(mu-trans-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-di(iodo)-di-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1047394: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tris(mu3-Iodo)-(mu2-iodo)-bis(mu2-dimethylsulfido)-(dimethylsulfido)-tetramethyl-tetra-copper)Experimental 3D Coordinates
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CCDC 1418781: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418772: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-bromo)-di-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974334: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu3-Iodo)-(mu2-bis(4-methoxyphenylthio)methane-SS')-di-copper)Experimental 3D Coordinates
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CCDC 1405449: Experimental Crystal Structure Determination

2015

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Space GroupCrystallography1'2'3'8'9'10'10a'10b'-octahydro-2H2''H-dispiro[acenaphthylene-15'-dipyrrolo[12-a:2'1'-c]pyrazine-6'1''-acenaphthylene]-22''-dioneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 830704: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters3-(4-methoxyphenyl)-4-phenyl-8b-(pyrrolidin-1-yl)-48b-dihydro-3aH-indeno[21-d][12]oxazoleExperimental 3D Coordinates
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CCDC 1418782: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418770: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]
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CCDC 1418765: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal Systemcatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974333: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal Systemcatena-(bis(mu3-Iodo)-(mu2-bis(p-tolylthio)methane-SS')-di-copper)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1047411: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu3-Bromo)-tris(mu2-ethyl methyl sulfide)-tris(mu2-bromo)-(ethyl methyl sulfide)-tetra-copper)Experimental 3D Coordinates
researchProduct

CCDC 947670: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(mu~4~-Bromo)-tetrakis(mu~3~-bromo)-tetrakis(mu~2~-bromo)-hexakis(mu~2~-methyl(propyl)thio)-deca-copper]
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CCDC 1047401: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographycatena-(tetrakis(mu3-Iodo)-(mu2-methyl n-propyl sulfide)-bis(methyl n-propyl sulfide)-tetra-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1479591: Experimental Crystal Structure Determination

2016

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catena-[bis(bis(mu-bromo)-(mu-1-(methylsulfanyl)-4-((((4-(methylsulfanyl)phenyl)sulfanyl)methyl)sulfanyl)benzene)-di-copper)]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1418776: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographybis(mu-bromo)-bis(mu-(11'-(but-2-ene-14-diylbis(sulfanediyl))dibenzene))-di-copperCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1418784: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1047396: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographycatena-(tetrakis(mu3-Iodo)-(mu2-ethyl methyl sulfide)-bis(ethyl methyl sulfide)-tetra-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1405447: Experimental Crystal Structure Determination

2015

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Space GroupCrystallography2'-(4-chlorophenyl)-1''-phenyl-5'6'7'7a'-tetrahydro-2''H5''H-dispiro[indole-33'-pyrrolizine-1'3''-pyrrolidine]-22''5''(1H)-trioneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 831070: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates4-Methyl-3-(4-methylphenyl)-8b-(morpholin-4-yl)-48b-dihydro-3aH-indeno[21-d][12]oxazole
researchProduct

CCDC 889646: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyN-(22-bis(piperidin-1-yl)vinyl)-11-diphenylmethanimineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 974326: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal Systemcatena-(bis(mu3-Iodo)-(mu2-bis(phenylthio)methane-SS')-di-copper)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 974341: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-bromo)-bis(acetonitrile)-bis(11'-(methylenedisulfanediyl)bis(2-methylbenzene))-di-copper(i)Experimental 3D Coordinates
researchProduct

CCDC 974324: Experimental Crystal Structure Determination

2014

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2015

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CCDC 1418769: Experimental Crystal Structure Determination

2016

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CCDC 974325: Experimental Crystal Structure Determination

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CCDC 941426: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdibromo-bis(mu-N-(2-(isopropylsulfanyl)-2-(isopropylsulfanyl)vinyl)-1-(4-(isopropylsulfanyl)phenyl)-1-(4-(isopropylsulfanyl)phenyl)methanimine)-di-copperExperimental 3D Coordinates
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2016

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Space GroupCrystallographycatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-bromo)-di-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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2016

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2016

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CCDC 1047412: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographycatena-(tetrakis(mu3-Iodo)-(mu2-methyl n-propyl sulfide)-bis(methyl n-propyl sulfide)-tetra-copper)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu3-Iodo)-(mu2-bis(4-bromophenylthio)methane-SS')-di-copper)Experimental 3D Coordinates
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2016

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2015

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2016

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2016

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2017

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2016

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CCDC 1047395: Experimental Crystal Structure Determination

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CCDC 1047413: Experimental Crystal Structure Determination

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2016

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