Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

6533b85cfe1ef96bd12bc96f

RESEARCH PRODUCT

Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

Michael Knorr Yoann Rousselin Isabelle Jourdain Ahmed Said Mohamed Marek M. Kubicki

subject

crystal structure metal–metal bond Silylation Stereochemistry chemistry.chemical_element Crystal structure Medicinal chemistry Research Communications lcsh:Chemistry chemistry.chemical_compound phosphido bridges [CHIM]Chemical Sciences General Materials Science diphenylmethylsilyl ligand ComputingMilieux_MISCELLANEOUS diphenylmethylsilyl ligand Ligand Tricarbon General Chemistry Condensed Matter Physics 3. Good health iron complexes lcsh:QD1-999 chemistry heterobimetallics Platinum platinum complexes

description

The title compound belongs to the large family of heterodinuclear phosphide-bridged complexes. The Fe—Pt bond is of 2.7738 (4) Å and there is an unprecedented arrangement of the silyl ligand in a trans-position with respect to the metal–metal vector in the family of phosphide-bridged iron–platinum heterobimetallics.

year	journal	country	edition	language
2015-01-01	Acta Crystallographica Section E Crystallographic Communications

https://doi.org/10.1107/s2056989015001565

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