6533b851fe1ef96bd12a9949
RESEARCH PRODUCT
4,4-Bis(4-methylphenylsulfanyl)-1,1-diphenyl-2-azabuta-1,3-diene
Marek M. KubickiRodolphe KinghatHamid BoudibaMichael KnorrAbderrahim Khatyrsubject
CrystallographyDiene010405 organic chemistryGeneral ChemistryDihedral angle010402 general chemistryCondensed Matter PhysicsBioinformaticsOrganic Papers01 natural sciencesMedicinal chemistry3. Good health0104 chemical scienceschemistry.chemical_compoundchemistryQD901-999General Materials ScienceVicinaldescription
In the title compound, C29H25NS2, both the Cl atoms of the azadiene precursor 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-azabutadiene array. The azadiene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly π-conjugated with the azadiene core [dihedral angle 5.1 (2)°].
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-10-23 | Acta Crystallographica Section E |