0000000000940856

AUTHOR

Andrea Zitolo

0000-0002-2187-6699

showing 3 related works from this author

The local atomic structure and thermoelectric properties of Ir-doped ZnO: hybrid DFT calculations and XAS experiments

2021

We greatly acknowledge the financial support via the ERAF Project No. 1.1.1.1/18/A/073. Calculations have been performed under the Project HPC-EUROPA3 (INFRAIA-2016-1-730897), with the support of the EC Research Innovation Action under the H2020 Programme. A. C. gratefully acknowledges the technical support received from KTH-PDC. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2

Materials scienceAbsorption spectroscopyExtended X-ray absorption fine structureFermi levelAnalytical chemistrychemistry.chemical_element02 engineering and technologyGeneral ChemistryElectronic structure010402 general chemistry021001 nanoscience & nanotechnology7. Clean energy01 natural sciences0104 chemical sciencessymbols.namesakechemistrySeebeck coefficientThermoelectric effect:NATURAL SCIENCES:Physics [Research Subject Categories]Materials ChemistrysymbolsDensity functional theoryIridium0210 nano-technologyJournal of Materials Chemistry C
researchProduct

Changes in structure and conduction type upon addition of Ir to ZnO thin films

2017

Zn-Ir-O (Zn/Ir ≈ 1/1) thin films have been reported to be a potential p-type TCO material. It is, however, unknown whether it is possible to achieve p-type conductivity at low Ir content, and how the type and the magnitude of conductivity are affected by the film structure. To investigate the changes in properties taking place at low and moderate Ir content, this study focuses on the structure, electrical and optical properties of ZnO:Ir films with iridium concentration varying between 0.0 and 16.4 at.%. ZnO:Ir thin films were deposited on glass, Si, and Ti substrates by DC reactive magnetron co-sputtering at room temperature. Low Ir content (up to 5.1 at.%) films contain both a nano-crysta…

Materials scienceThin filmsAnalytical chemistrychemistry.chemical_element02 engineering and technologyConductivity010402 general chemistryIridium01 natural sciencesIonCrystallinityElectrical resistivity and conductivityMaterials Chemistry:NATURAL SCIENCES:Physics [Research Subject Categories]IridiumThin filmAmorphous doped ZnOMetals and AlloysSurfaces and Interfaces021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAmorphous solidchemistryCrystallite0210 nano-technologyReactive DC magnetron co-sputtering
researchProduct

Tuning the Structure of Galacturonate Hydrogels: External Gelation by Ca, Zn, or Fe Cationic Cross-Linkers

2019

International audience; We show here how the nature of various divalent cations M2+ (Ca2+, Zn2+, or Fe2+) influences the structure and mechanical properties of ionotropic polygalacturonate (polyGal) hydrogels designed by the diffusion of cations along one direction (external gelation). All hydrogels exhibit strong gradients of polyGal and cation concentrations, which are similar for all studied cations with a constant ratio R = [M2+]/[Gal] equal to 0.25, showing that every M2+ cation interacts with four galacturonate (Gal) units all along the gels. The regions of the hydrogels formed in the early stages of the gelation process are also similar for all cations and are homogeneous, with the s…

DenticityPolymers and PlasticsDiffusionIronBioengineering02 engineering and technology010402 general chemistry01 natural sciencesDivalentBiomaterialsCations[SDV.IDA]Life Sciences [q-bio]/Food engineeringMaterials ChemistrypolyGal and cation concentrationsColloidschemistry.chemical_classificationChemistryHexuronic AcidsCationic polymerizationHydrogelsDynamic mechanical analysis021001 nanoscience & nanotechnologySmall-angle neutron scattering0104 chemical sciencesionotropic polygalacturonate (polyGal) hydrogelsCrystallographyZincCross-Linking ReagentsHomogeneousSelf-healing hydrogelsCalcium0210 nano-technology
researchProduct