0000000000942299

AUTHOR

Sonja Durdevic

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A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters.

2013

International audience; Combining serendipitously-formed hydroxo-clusters, [CoII3(OH)(piv)4(L)]+ (where L = MeCN or Hpiv), with assembling cyanide building block, [FeIII(Tp)(CN)3]−, has led to an unprecedented architecture where polymetallic cobalt clusters and blocked tris-cyanide iron complexes define the apexes of a unique magnetic cubic nanocage.

010405 organic chemistryCyanideInorganic chemistryMetals and Alloyschemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundCrystallographyNanocageschemistryBlock (telecommunications)Materials ChemistryCeramics and Composites[CHIM.COOR]Chemical Sciences/Coordination chemistryCobaltChemical communications (Cambridge, England)
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