6533b853fe1ef96bd12acbbe
RESEARCH PRODUCT
A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters.
Laurent LisnardRodrigue LescouëzecLise-marie ChamoreauAbhishake MondalYves JournauxSonja DurdevicMiguel Julvesubject
010405 organic chemistryCyanideInorganic chemistryMetals and Alloyschemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundCrystallographyNanocageschemistryBlock (telecommunications)Materials ChemistryCeramics and Composites[CHIM.COOR]Chemical Sciences/Coordination chemistryCobaltdescription
International audience; Combining serendipitously-formed hydroxo-clusters, [CoII3(OH)(piv)4(L)]+ (where L = MeCN or Hpiv), with assembling cyanide building block, [FeIII(Tp)(CN)3]−, has led to an unprecedented architecture where polymetallic cobalt clusters and blocked tris-cyanide iron complexes define the apexes of a unique magnetic cubic nanocage.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-01-09 | Chemical communications (Cambridge, England) |