0000000000963434

AUTHOR

M. Luisa García-sanz De Larrea

showing 2 related works from this author

Unravelling the chemical design of spin-crossover nanoparticles based on iron(ii)–triazole coordination polymers: towards a control of the spin trans…

2015

We present a systematic study of the key synthetic parameters that control the growth of Fe–triazole spin-crossover nanoparticles and the effect of this size modulation on the spin transition.

ChemistryCondensed Matter::Strongly Correlated ElectronsJournal of Materials Chemistry. C, Materials for Optical and Electronic Devices
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Unravelling the chemical design of spin-crossover nanoparticles based on iron(ii)–triazole coordination polymers: towards a control of the spin trans…

2015

A systematic study of the key synthetic parameters that control the growth of spin-crossover (SCO) nanoparticles (NPs) using the reverse micelle technique has been undertaken in the system [Fe(Htrz)2(trz)](BF4)·H2O, (Htrz = 1,2,4-triazole). This has permitted us to modulate the physical properties of the NPs in a controlled and reproducible manner. In particular, a control over the size of the NPs (in the range 4 to 16 nm) has been achieved by varying the water to surfactant molar ratio. The consequences of this size variation on the cooperativity of the spin transition are discussed. Finally, this approach has been extended to the chemical alloy [Fe(Htrz)2.95(NH2trz)0.05](ClO4)2 in order t…

chemistry.chemical_classificationMaterials scienceAlloySpin transitionNanoparticleCooperativityNanotechnology02 engineering and technologyGeneral ChemistryPolymerengineering.material010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesMicelle0104 chemical sciencesPulmonary surfactantchemistrySpin crossoverMaterials ChemistryengineeringPhysical chemistry0210 nano-technologyJournal of Materials Chemistry C
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