Author: Maxime Boudjelel

0000000000985495

AUTHOR

Maxime Boudjelel

0000-0001-8347-0574

showing 3 related works from this author

A sterically congested 1,2-diphosphino-1'-boryl-ferrocene: synthesis, characterization and coordination to platinum.

2019

International audience; A new class of tritopic ferrocene-based ambiphilic compound has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformation constraints, as apparent from XRD and NMR data, but does not prevent chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.

Steric effects010405 organic chemistryChemistryLigandchemistry.chemical_element010402 general chemistry01 natural sciencesNmr data3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundFerrocenePolymer chemistry[CHIM]Chemical SciencesMoietyChelationLewis acids and basesPlatinumDalton transactions (Cambridge, England : 2003)

researchProduct

CCDC 1902394: Experimental Crystal Structure Determination

2019

Related Article: Emmanuel Lerayer, Patrice Renaut, Julien Roger, Nadine Pirio, Hélène Cattey, Paul Fleurat-Lessard, Maxime Boudjelel, Stéphane Massou, Ghenwa Bouhadir, Didier Bourissou, Jean-Cyrille Hierso|2019|Dalton Trans.|48|11191|doi:10.1039/C9DT01921A

Space GroupCrystallographyCrystal System12-bis(diphenylphosphino)-1'-(dimesitylboryl)-3'4-di-t-butylferroceneCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1902395: Experimental Crystal Structure Determination

2019

Related Article: Emmanuel Lerayer, Patrice Renaut, Julien Roger, Nadine Pirio, Hélène Cattey, Paul Fleurat-Lessard, Maxime Boudjelel, Stéphane Massou, Ghenwa Bouhadir, Didier Bourissou, Jean-Cyrille Hierso|2019|Dalton Trans.|48|11191|doi:10.1039/C9DT01921A

Space GroupCrystallography(mu-4-t-butyl-12-bis(diphenylphosphanyl)cyclopenta-24-dien-1-yl)-(2-[bis(246-trimethylphenyl)boranyl]-4-t-butylcyclopenta-24-dien-1-yl)-bis(chloro)-platinum(ii)-iron dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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