6533b855fe1ef96bd12b12df
RESEARCH PRODUCT
A sterically congested 1,2-diphosphino-1'-boryl-ferrocene: synthesis, characterization and coordination to platinum.
Stéphane MassouPatrice RenautHélène CatteyJulien RogerGhenwa BouhadirPaul Fleurat-lessardJean-cyrille HiersoDidier BourissouEmmanuel LerayerNadine PirioMaxime Boudjelelsubject
Steric effects010405 organic chemistryChemistryLigandchemistry.chemical_element010402 general chemistry01 natural sciencesNmr data3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundFerrocenePolymer chemistry[CHIM]Chemical SciencesMoietyChelationLewis acids and basesPlatinumdescription
International audience; A new class of tritopic ferrocene-based ambiphilic compound has been prepared by assembling diphosphino- and boryl-substituted cyclopentadienides at iron. The presence of five sterically demanding substituents on the ferrocene platform induces conformation constraints, as apparent from XRD and NMR data, but does not prevent chelating coordination to platinum. The Lewis acid moiety is pendant in both the free ligand and the platinum complex.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-07-13 | Dalton transactions (Cambridge, England : 2003) |