0000000000988084
AUTHOR
Beatrice Braun-cula
In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)
Two new examples of cyanido-bridged {FeIIILnIII}2 molecular squares, with pyim and PPh3O as capping ligands at the LnIII sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh3PO = triphenylphosphine oxide].
Synthesis, Crystal Structure and Magnetic Properties of Three {Cr III Mn II } Heterodimetallic Complexes Based on Heteroleptic Cyanido‐Bearing Cr III Building Blocks
The use of the heteroleptic [CrIII(AA)(CN)4]- complex as a ligand towards the preformed [MnII(tptz)]2+ and [MnII(pyim)2]2+ species afforded the heterometallic compounds: [MnII(tptz)(H2O)(NO3)(-NC)CrIII(ampy)(CN)3]CH3CN (1), [MnII(tptz)(H2O)(NO3)(-NC)CrIII(phen)(CN)3]H2O (2) and {[MnII(pyim)2][(-NC)Cr(phen)(CN)3]2}3H2O (3) [AA = 2-aminomethylpyridine (ampy) and 1,10-phenanthroline (phen), tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine and pyim = 2-(1H-imidazol-2-yl)pyridine]. 1 and 2 are neutral heterodinuclear complexes where a [CrIII(AA)(CN)4]- building block acts as a monodentate ligand through one cyanide group towards a seven coordinate MnII ion. Compound 3 is a neutral heterotrinuclear co…
CCDC 1907945: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Sergiu Shova, Francesc Lloret, Miguel Julve|2019|Dalton Trans.|48|7532|doi:10.1039/C9DT01445D
CCDC 1524159: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Francesc Lloret, Miguel Julve|2018|Eur.J.Inorg.Chem.||349|doi:10.1002/ejic.201700313
CCDC 1524158: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Francesc Lloret, Miguel Julve|2018|Eur.J.Inorg.Chem.||349|doi:10.1002/ejic.201700313
CCDC 1524157: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Francesc Lloret, Miguel Julve|2018|Eur.J.Inorg.Chem.||349|doi:10.1002/ejic.201700313
CCDC 1907944: Experimental Crystal Structure Determination
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Sergiu Shova, Francesc Lloret, Miguel Julve|2019|Dalton Trans.|48|7532|doi:10.1039/C9DT01445D