6533b855fe1ef96bd12b1b09
RESEARCH PRODUCT
In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)
Beatrice Braun-culaSergiu ShovaMaria-gabriela AlexandruFrancesc LloretMiguel JulveDiana Visinescusubject
Inorganic ChemistryIn situCrystallographychemistry.chemical_compound010405 organic chemistryChemistryPyridineAntiferromagnetism010402 general chemistry01 natural sciencesTriphenylphosphine oxide0104 chemical sciencesdescription
Two new examples of cyanido-bridged {FeIIILnIII}2 molecular squares, with pyim and PPh3O as capping ligands at the LnIII sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh3PO = triphenylphosphine oxide].
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-01-01 | Dalton Transactions |