0000000000278370

AUTHOR

Sergiu Shova

showing 102 related works from this author

Dinuclear manganese(iii) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectro…

2019

Three dimanganese(iii) complexes have been synthesised and fully characterised by standard spectroscopic methods and spectroelectrochemistry. Each MnIII ion is chelated by a salen type ligand (H2L), but there is variation in the bridging group: LMn(OOCCH[double bond, length as m-dash]CHCOO)MnL, LMn(OOCC6H4COO)MnL, and LMn(OOCC6H4C6H4COO)MnL. X-ray diffraction revealed an axial compression of each six-coordinate high-spin d4 MnIII ion, which is a Jahn-Teller-active ion. Temperature dependent magnetic susceptibility and variable temperature-variable field (VTVH) magnetisation measurements, as well as high-frequency and -field EPR (HFEPR) spectroscopy were used to accurately describe the magne…

Materials scienceAbsorption spectroscopy010405 organic chemistryExchange interactionchemistry.chemical_elementManganese010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical scienceslaw.inventionIonInorganic ChemistryCrystallographyMagnetizationchemistrylawElectron paramagnetic resonanceSpectroscopyDalton Transactions
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Three different types of bridging ligands in a 3d-3d'-3d'' heterotrimetallic chain.

2017

A one-pot synthesis of a 3d–3d′–3d′′ heterotrimetallic coordination polymer with double diphenoxido, single cyanido and bis-bidentate oxalate as alternating bridges which exhibits an overall antiferromagnetic behaviour has been developed.

Inorganic Chemistrychemistry.chemical_compoundCrystallographyBridging (networking)chemistry010405 organic chemistryCoordination polymer010402 general chemistry01 natural sciencesOxalate0104 chemical sciencesDalton transactions (Cambridge, England : 2003)
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Field-induced single ion magnet behaviour of discrete and one-dimensional complexes containing [bis(1-methylimidazol-2-yl)ketone]-cobalt(II) building…

2021

International audience; We describe herein the first examples of six-coordinate CoII single-ion magnets (SIMs) based on the β-diimine Mebik ligand [Mebik = bis(1-methylimidazol-2-yl)ketone]: two mononuclear [CoII(Rbik)2L2] complexes and one mixed-valence {CoIII2CoII}n chain of formulas [CoII(Mebik)(H2O)(dmso)(μ-NC)2CoIII2(μ-2,5-dpp)(CN)6]n·1.4nH2O (3) [L = NCS (1), NCSe (2) and 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine (3)]. Two bidentate Mebik molecules plus two monodentate N-coordinated pseudohalide groups in cis positions build somewhat distorted octahedral surroundings around the high-spin cobalt(II) ions in 1 and 2. The diamagnetic [CoIII2(μ-2,5-dpp)(CN)8]2− metalloligand coordinates the pa…

DenticityMaterials sciencePyrazine010405 organic chemistrychemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical scienceslaw.inventionInorganic ChemistryMagnetizationCrystallographyParamagnetismMagnetic anisotropychemistry.chemical_compoundchemistrylaw[CHIM]Chemical SciencesMoleculeElectron paramagnetic resonanceCobaltDalton transactions (Cambridge, England : 2003)
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A five-coordinate manganese(iii) complex of a salen type ligand with a positive axial anisotropy parameter D.

2017

A new high-spin d4 roughly trigonal–bipyramidal (TBP) manganese(III) complex with a salen type ligand (H2L), namely MnL(NCS)·0.4H2O, has been synthesised and characterised by elemental analysis, ESI mass spectrometry, IR and UV-vis spectroscopy, and spectroelectrochemistry. X-ray diffraction analysis revealed an axial compression of the approximate TBP. Temperature dependent magnetic susceptibility and variable-temperature variable-field (VTVH) magnetisation measurements, as well as high-frequency and -field EPR (HFEPR) spectroscopy, were used to accurately describe the magnetic properties of this complex and, in particular, determine the spin Hamiltonian parameters: g-values and the zero-f…

Absorption spectroscopy010405 organic chemistryAnalytical chemistrychemistry.chemical_elementManganese010402 general chemistry01 natural sciencesMagnetic susceptibilitySpectral line0104 chemical scienceslaw.inventionInorganic ChemistryMagnetizationchemistrylawPhysical chemistryElectron paramagnetic resonanceAnisotropySpectroscopyDalton transactions (Cambridge, England : 2003)
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Hofmann-Like Frameworks Fe(2-methylpyrazine)n[M(CN)2]2 (M = Au, Ag) : Spin-Crossover Defined by the Precious Metal

2020

Hofmann-like cyanometalates constitute a large class of spin-crossover iron(II) complexes with variable switching properties. However, it is not yet clearly understood how the temperature and cooperativity of a spin transition are influenced by their structure. In this paper, we report the synthesis and crystal structures of the metal–organic coordination polymers {FeII(Mepz)[AuI(CN)2]2} ([Au]) and {FeII(Mepz)2[AgI(CN)2]2} ([Ag]), where Mepz = 2-methylpyrazine, along with characterization of their spin-state behavior by variable-temperature SQUID magnetometry and Mössbauer spectroscopy. The compounds are built of cyanoheterometallic layers, which are pillared by the bridging Mepz…

chemistry.chemical_classificationLarge classOorganisk kemi010405 organic chemistryIronSpin transitionCooperativityPolymerCrystal structureAtmospheric temperature range010402 general chemistrySpin crossover01 natural sciences0104 chemical sciencesInorganic ChemistryCrystallographychemistrySpin crossovermagnetismMössbauer spectroscopyPhysical and Theoretical ChemistryMOF
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Room temperature hysteretic spin crossover in a new cyanoheterometallic framework.

2019

A new iron(II)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported. This complex exhibits a high reproducibility of the spin transition in many successive thermal cycles, stability of both spin states at room temperature and an attractive operational temperature range.

Range (particle radiation)Thermal hysteresisMaterials scienceSpin statesCondensed matter physics010405 organic chemistryMetals and AlloysSpin transitionGeneral Chemistry010402 general chemistryOperation temperature01 natural sciences7. Clean energyCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSpin crossoverThermalMaterials ChemistryCeramics and CompositesCondensed Matter::Strongly Correlated ElectronsChemical communications (Cambridge, England)
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The first example of a hetero-tetranuclear [(VO)Gd](2) complex: synthesis, crystal structure and magnetic properties of [VOLGd(hfa)(2)CH(3)OH](2).2CH…

2005

A cyclic tetranuclear [VIVO–GdIII]2 complex with VO and Gd ions alternately arrayed, behaves, from the magnetic point of view, as two independent dinuclear entities each having a S = 4 ground state, as a consequence of an active and ferromagnetic VO–Gd interaction through the double phenoxo bridge and a magnetically inactive VO–Gd interaction through the amide bridge.

Inorganic Chemistrychemistry.chemical_compoundCrystallographyFerromagnetismChemistryStereochemistryAmideCrystal structureGround stateIonDalton transactions (Cambridge, England : 2003)
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Two-Dimensional Coordination Polymers Constructed by [NiIILnIII] Nodes and [WIV(bpy)(CN)6]2– Spacers: A Network of [NiIIDyIII] Single Molecule Magnets

2013

Three isomorphous two-dimensional (2D) coordination polymers of general formula {[Ni(II)(valpn)Ln(III)(NO3)(H2O)(μ-NC)4W(IV)(bipy)(CN)2]·xH2O·yCH3CN}n have been synthesized by reacting Ph4P[W(V)(CN)6(bipy)] with the heterodinuclear [Ni(II)Ln(III)(valpn)(O2NO)3] complexes [H2valpn = 1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol), bipy = 2,2'-bipyridine, and Ln = Gd (1), Dy (2), and Tb (3) with x = 2 (1), 3.9 (2), and 3.35 (3) and y = 2.50 (1), 2 (2), and 1.8 (3)]. Their crystal structures consist of [Ni(II)Ln(III)] 3d-4f nodes which are connected by [W(IV)(bipy)(CN)6](2-) diamagnetic linkers resulting from the reduction of W(V) to W(IV) during the reaction process. The Ni(II) and Ln(I…

Inorganic Chemistrychemistry.chemical_classificationCrystallographyOxygen atomChemistryLigandStereochemistryMoleculePolymerCrystal structurePhysical and Theoretical ChemistryIonInorganic Chemistry
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Cyanido-bridged {FeIIILnIII} heterobimetallic chains assembled through the [FeIII{HB(pz)3}(CN)3]−complex as metalloligand: synthesis, crystal structu…

2021

A new series of cyanido-bridged {FeIIILnIII} heterobimetallic chains of general formula {[(NC)FeIII{HB(pz)3}(μ-CN)2LnIII(bpdo)(NO3)2(H2O)]·CH3CN}n [HB(pz)3− = hydrotris(pyrazol-1-yl)borate, bpdo = 2,2′-bipyridine-N,N′-dioxide and Ln = Gd (1), Tb (2), Dy (3) and Ho (4)], were obtained by using the low-spin [Fe{HB(pz)3}(CN)3]− complex as a metalloligand towards the preformed [Ln(bdpo)(NO3)2(H2O)]+ species. Single-crystal X-ray diffraction shows that 1–4 are isostructural compounds that crystallize in the monoclinic P21/c space group. Their crystal structure consists of neutral 1D coordination polymers where the [Fe{HB(pz)3}(CN)3]− fragment adopts a bis-monodentate coordination mode, through t…

Ligand field theoryLanthanideCrystallographyMaterials scienceCoordination sphereOctahedronLigandGeneral Materials ScienceGeneral ChemistryCrystal structureIsostructuralCondensed Matter PhysicsMonoclinic crystal systemCrystEngComm
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Synthesis, crystal structure and magnetic properties of a new [ZnII6DyIII6] dodecanuclear motif

2013

Abstract A new dodecanuclear complex, [{(HL)(L)(dmf)ZnIIDyIII(dmf)(H2O)}6]·3dmf·4.2H2O has been assembled using a supramolecular compartmental ligand (H3L results from the condensation reaction of 3-formylsalicylic acid and hydroxylamine). The six DyIII ions describe an octahedron that is inscribed into the octahedron generated by the zinc(II) ions each DyIII ion from this motif behaving as a single ion magnet.

ChemistryStereochemistryLigandSupramolecular chemistrychemistry.chemical_elementCrystal structureZincCondensation reactionIonInorganic Chemistrychemistry.chemical_compoundCrystallographyHydroxylamineOctahedronMaterials ChemistryPhysical and Theoretical ChemistryPolyhedron
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Cyanido-Bridged {LnIIIWV} Heterobinuclear Complexes: Synthesis and Magneto-Structural Study

2017

A new series of cyanido-bridged {LnIIIWV} heterobinuclear complexes of formula [LnIII(pyim)2(i-PrOH)(H2O)2(μ-CN)WV(CN)7]·2H2O [Ln = Gd (1), Tb (2), Dy (3), Ho (4), and Er (5); pyim = 2-(1H-imidazol-2-yl)-pyridine) and i-PrOH = isopropyl alcohol] were synthesized by one-pot reaction between (NH3Bu)3[W(CN)8] and [Ln(pyim)2]2+ complexes (generated in situ by mixing the corresponding LnIII ions and the pyim ligand). Compounds 1–5 are isomorphous and crystallize in the monoclinic system P21/n space group. Their crystal structure consists of binuclear units in which the octacyanotungstate(V) anion coordinates to the corresponding LnIII ion through a single cyanide ligand. The tungsten(V) and lant…

Lanthanide010405 organic chemistryChemistryStereochemistryLigandCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonSquare antiprismInorganic ChemistryDodecahedronCrystallographyAntiferromagnetismPhysical and Theoretical ChemistryMonoclinic crystal systemInorganic Chemistry
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An original 1D Cu–Co heterometallic compound: synthesis, structure and magnetic properties

2006

A novel heterobimetallic system, 1∞[LCuIICoII(NCS)2] (1), was obtained by reacting the neutral mononuclear complex [LCu] with cobalt(II) acetate in the presence of potassium thiocyanate (L is the dianion of the Schiff base resulting from the 2 ∶ 1 condensation of 3-methoxysalicylaldehyde with 1,3-propanediamine). The crystallographic investigation of 1 reveals a one-dimensional alternating zig-zag chain-like structure, made of dinuclear {LCuCo} units linked by thiocyanate bridges. The copper(II) ion is pentacoordinate to the N2O2 donor set of the Schiff base ligand in the basal plane, with the apical position occupied by the sulfur atom. The cobalt ion displays a strongly distorted (4 + 2) …

Schiff baseThiocyanateChemistryLigandExchange interactionInorganic chemistrychemistry.chemical_elementGeneral ChemistryCatalysischemistry.chemical_compoundCrystallographyPotassium thiocyanateOctahedral molecular geometryMaterials ChemistryAntiferromagnetismCobaltNew Journal of Chemistry
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Aggregation of [Ln(12)(III)] clusters by the dianion of 3-formylsalicylic acid. Synthesis, crystal structures, magnetic and luminescence properties

2019

Three isostrucutral dodecanuclear clusters with the general formula [Ln(12)(fsa)(12)(mu f(3)-OH)(12)(DMF)(12)]center dot nDMF (fsa(2-) is the dianion of 3-formylsalicylic acid; Ln = Eu 1, Gd 2, Dy 3) have been obtained from the reaction of fromylsalicyclic acid (H(2)fsa), tetrabutylammonium hydroxide and Ln(NO3)(3)center dot 6H(2)O in methanol/DMF. Their structure consists of four vertex-sharing heterocubanes. Each heterocubane unit is assembled from four Ln(III) ions, three mu(3)-OH groups and one mu(3)-oxygen atom arising from the fsa(2-) carboxylato group. The photophysical properties of the europium derivative investigated at both 300 and 80 K sustain a relative intense emission obtaine…

---Materials science010405 organic chemistryTetrabutylammonium hydroxidechemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAtomDysprosiumMagnetic refrigerationEuropiumLuminescence
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Azine-bridged octanuclear copper(II) complexes assembled with a one-stranded ditopic thiocarbohydrazone ligand.

2005

Models MolecularMolecular StructureLigandNitrogenHydrazoneschemistry.chemical_elementGeneral MedicineGeneral ChemistryLigandsCopperCatalysisAzinechemistry.chemical_compoundchemistryPolymer chemistryOrganometallic CompoundsSulfhydryl CompoundsAzo CompoundsCopperAngewandte Chemie (International ed. in English)
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Magnetism in Heterobimetallic and Heterotrimetallic Chains Based on the Use of [W V (bipy)(CN) 6 ] – as a Metalloligand

2018

Inorganic ChemistryCrystallography010405 organic chemistryChemistryMagnetismSelf-assembly010402 general chemistry01 natural sciences0104 chemical sciencesEuropean Journal of Inorganic Chemistry
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Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain

2017

The assembly reaction between the low-spin [CoII(dmphen)(CN)3]- metalloligand and the [MnIII(salen)(H2O)]+ complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n (1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = -1.71(1) cm-1.

010405 organic chemistryStereochemistryCyanideCrystal structure010402 general chemistry01 natural sciencesInductive coupling0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryChain (algebraic topology)FerrimagnetismDalton Transactions
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Spontaneous Resolution of a Triple‐Stranded Dinickel(II) Helicate Generated via Intermolecular Transamination Reaction of S ‐Methylisothiocarbohydraz…

2008

The reaction of S-methylisothiocarbohydrazide hydroiodide [H2NNHC(SCH3)NNH2·HI] with NiCl2·6H2O in water at room temperature yielded a triple-stranded dinickel(II) helicate [NiII(L1–L1)3NiII]I4·4H2O (14+·4I–·4H2O), where L1–L1 = H2NNHC(SCH3)NNC(SCH3)NHNH2, in 35 % yield, which spontaneously separates in enantiomers upon crystallization. The enantiomers do not racemize at room temperature, even not after 15 h of heating at 90 °C. X-ray diffraction structures of both enantiomers, chiroptical and magnetic properties of 14+·4I–·4H2O are reported. Demetallation of the complex by treatment with S2– resulted in 3,6-bis(methylthio)-1,4-dihydro-1,2,4,5-tetrazine (2). Compound 2 undergoes 2-e– oxidat…

Inorganic Chemistrychemistry.chemical_classificationCrystallographyChemistrylawTransaminationStereochemistryYield (chemistry)Intermolecular forceResolution (electron density)CrystallizationEnantiomerlaw.inventionEuropean Journal of Inorganic Chemistry
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In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)

2019

Two new examples of cyanido-bridged {FeIIILnIII}2 molecular squares, with pyim and PPh3O as capping ligands at the LnIII sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh3PO = triphenylphosphine oxide].

Inorganic ChemistryIn situCrystallographychemistry.chemical_compound010405 organic chemistryChemistryPyridineAntiferromagnetism010402 general chemistry01 natural sciencesTriphenylphosphine oxide0104 chemical sciencesDalton Transactions
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An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers

2021

A novel 3D coordination polymer, ∞3[{Cu3(felden)}4(btec)3]·17H2O, has been assembled using cationic trigonal nodes, [CuII3(felden)]3+, generated by a tricompartmental ligand, H3felden, which results from the Schiff condensation reaction between 2,4,6-triformylphloroglucinol and N,N-dimethylethylenediamine. The tetraanion of the 1,2,4,5-benzenetetracaboxylic acid (H4btec) was employed as a spacer. The structure of 1 shows large icosahedral cavities and channels and the magnetic interaction between the copper(II) ions within the triangles is weak and antiferromagnetic.

Materials scienceLigandCoordination polymerIcosahedral symmetryCationic polymerizationchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsCondensation reactionCopperIonCrystallographychemistry.chemical_compoundchemistryAntiferromagnetismGeneral Materials ScienceCrystEngComm
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Slow relaxation of the magnetization in a {CoIIIMnIII} heterometallic brick-wall network

2021

Abstract The use of the cyanide-bearing dicobalt(III) complex (PPh4)2[Co2III(μ−2,5-dpp)(CN)8] as a metalloligand towards [Mn(salen)(H2O)]ClO4 afforded the heterobimetallic two-dimensional compound of formula [{MnIII(salen)}2{(μ-NC)4Co2III(μ−2,5-dpp)(CN)4}]n (1) [PPh4+ = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H2salen = N,N’-ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co2III(μ−2,5-dpp)(CN)8]2− unit adopts a tetrakis-monodentate bridging mode towards four {MnIII(salen)}+ fragments through four of its eight cyanide ligands. Each cobalt(III)…

Pyrazine010405 organic chemistryChemistryRelaxation (NMR)chemistry.chemical_elementManganese010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic ChemistryMagnetizationchemistry.chemical_compoundCrystallographyOctahedronMaterials ChemistryMoleculePhysical and Theoretical ChemistrySingle crystalPolyhedron
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Synthesis, Crystal Structures, and Magnetic Properties of Two Novel Cyanido-Bridged Heterotrimetallic {CuIIMnIICrIII} Complexes

2017

The self-assembly process between the heteroleptic [CrIII(phen)(CN)4]− and [CrIII(ampy)(CN)4]− metalloligands and the heterobimetallic {CuII(valpn)MnII}2+ tecton afforded two heterotrimetallic complexes of formula [{CuII(valpn)MnII(μ-NC)2CrIII(phen)(CN)2}2{(μ-NC)CrIII(phen)(CN)3}2]·2CH3CN (1) and {[CuII(valpn)MnII(μ-NC)2CrIII(ampy)(CN)2]2·2CH3CN}n (2) [phen = 1,10-phenanthroline, ampy = 2-aminomethylpyridine, and H2valpn = 1,3-propanedyilbis(2-iminomethylene-6-methoxyphenol)]. The crystal structure of 1 consists of neutral CuII2MnII2CrIII4 octanuclear units, where two [Cr(phen)(CN)4]− anions act as bis-monodentate ligands through cyanide groups toward two manganese(II) ions from two [CuII(v…

010405 organic chemistryStereochemistryCoordination polymerCyanidechemistry.chemical_elementCrystal structureManganese010402 general chemistry01 natural sciencesCopper0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryPhysical and Theoretical ChemistryInorganic Chemistry
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Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d-4f clusters.

2015

Two types of oxalato-bridged heterometallic 3d–4f dodeca- and hexanuclear compounds have been obtained by connecting six bi- and, respectively, trinuclear moieties through oxalato bridges arising from the slow decomposition of the L-ascorbic acid.

Inorganic Chemistrychemistry.chemical_compoundchemistrySimple (abstract algebra)Inorganic chemistryAscorbic acidDecompositionOxalateIonDalton transactions (Cambridge, England : 2003)
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Design of 3d–4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]− metalloligand

2018

A new series of {FeIII2LnIII2} heterobimetallic squares of general formula [FeIII{HB(pz)3}(CN)(μ-CN)2Ln(pyim)x(NO3)2(H2O)y]2·zH2O [Ln = La (1), Gd (2), Tb (3) and Dy (4); {HB(pz)3}− = hydrotris(pyrazolyl)borate and pyim = 2-(1H-imidazol-2-yl)pyridine; x = 2, y = 0 (1), x = y = 1 (2–4) and z = 10 (1), 6 (2), 2.76 (3), 4 (4)] were synthesized by reacting the low-spin [FeIII{HB(pz)3}(CN)3]− complex anion with the preformed [LnIII(pyim)x(NO3)2(H2O)y]+ complex cation [formed in situ by mixing the lanthanide(III) salt and the pyim ligand]. Single-crystal X-ray diffraction shows that 1–4 crystallize in the P triclinic space group, 2–4 being isomorphous. In all cases, the structure comprises neutra…

LanthanideLigand field theory010405 organic chemistryLigandHydrogen bondSupramolecular chemistry010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryOctahedronPyridineDalton Transactions
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A new chiral dimanganese(iii) complex: synthesis, crystal structure, spectroscopic, magnetic, and catalytic properties

2016

Two enantiomeric complexes of formula [MnIII2(μ-OCH3)2(R-valBINAM)2]·1.75DMF (1) and [MnIII2(μ-OCH3)2(S-valBINAM)2]·2DMF (2) [valBINAM = 1,1′-binaphthalene-2,2′-bis(3-methoxysalicylideneiminate)] have been synthesized using as a ligand the chiral Schiff bases resulting from the condensation reactions between o-vanillin and the chiral 1,1′-binaphthyl-2,2′-diamine. The structures of 1 and 2 which have been solved by single crystal X-ray diffraction consist of neutral dimers, the manganese(III) ions being bridged by two methoxido anions, arising from the solvent, and by two valBINAM2− ligands. Their circular dichroism spectra at room temperature emphasize the occurrence of the exciton coupling…

010405 organic chemistryLigandGeneral Chemical EngineeringInorganic chemistrychemistry.chemical_elementGeneral ChemistryManganeseCrystal structure010402 general chemistryCondensation reaction01 natural sciences0104 chemical sciencesCatalysisSolventCrystallographychemistryEnantiomerSingle crystalRSC Advances
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Structural Transformations and Magnetic Effects Induced by Solvent Exchange in the Spin Crossover Complex [Fe(bpp) 2 ][Cr(bpy)(ox) 2 ] 2

2005

Structural, thermal, magnetic and solvent-exchange properties of the spin crossover compound [Fe(bpp)2][Cr(bpy)(ox)2]2 containing paramagnetic anions are given. This complex salt 1 crystallises as a dihydrate with two inequivalent (high-spin and low-spin) FeII sites. The dehydrated compound is a spin-crossover material with T1/2 ↑ = 369 K and T1/2 ↓ = 353 K. Rehydration takes place without loss of crystallinity, yielding a polymorph (2) with 100 % high-spin Fe II sites. The different high-spin fractions in 1 and 2 have been correlated to structural changes in the FeII second coordination sphere. The magnetic response to the presence of different sorbed molecules has also been explored. © Wi…

Inorganic ChemistrySolventchemistry.chemical_classificationCrystallographyCrystallinityParamagnetismCoordination sphereNuclear magnetic resonancechemistrySpin crossoverMoleculeSalt (chemistry)Magnetic responseEuropean Journal of Inorganic Chemistry
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Homo- and heterometallic complexes constructed from hexafluoroacetylacetonato and Schiff-base complexes as building-blocks

2018

Three new homo- and heterotrimetallic complexes have been synthesized and crystallographically characterized: [Cu2(saldmpn)2(μ-OCH3)2Cu2(hfac)2] (1), [Ni2(valaepy)2(hfac)2] (2), [Cu(saldmpn)Co(hfac)2] (3) [H2saldmpn is the Schiff-base resulting from condensation of salicylaldehyde with 2,2-dimethyl-1,3-diaminopropane and Hvalaepy results from the reaction of o-vanillin with 2-(2-aminoethyl)pyridine)]. The structure of 1 consists of a neutral tetranuclear species that can be viewed as resulting from mutual coordination of one {(hfac)Cu(μ-OCH3)2(Cu(hfac)} and two {Cu(saldmpn)} building blocks. Compound 2 is a binuclear complex that results from two {Ni(hfac)(valaepy} fragments, the nickel(II)…

Schiff base010405 organic chemistryCondensationchemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical sciencesIonCrystallographychemistry.chemical_compoundNickelchemistryFerromagnetismSalicylaldehydePyridineMaterials ChemistryPhysical and Theoretical ChemistryCobaltJournal of Coordination Chemistry
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Slow Relaxation of the Magnetization in a {Co <sup>III</sup>Mn <sup>III</sup>} Heterometallic Brick-Wall Network

2021

The use of the cyanide-bearing dicobalt(III) complex (PPh 4 ) 2 [Co 2 III (m-2,5-dpp)(CN) 8 ] as a metalloligand towards [Mn(salen)(H 2 O)]ClO 4 afforded the heterobimetallic two-dimensional compound of formula [{Mn III (salen)} 2 {(m-NC) 4 Co 2 III (m-2,5-dpp)(CN) 4 }] n (1) [PPh 4 + = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H 2 salen = N,N’ -ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co 2 III (m-2,5-dpp)(CN) 8 ] 2- unit adopts a tetrakis-monodentate bridging mode towards four {Mn III (salen)} + fragments through four of its eight cyan…

chemistry.chemical_compoundCrystallographyMagnetizationMaterials scienceOctahedronPyrazinechemistryRelaxation (NMR)chemistry.chemical_elementMoleculeManganeseSingle crystalCobaltSSRN Electronic Journal
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Two-Dimensional Coordination Polymers Constructed Using, Simultaneously, Linear and Angular Spacers and Cobalt(II) Nodes. New Examples of Networks of…

2014

Two novel bidimensional coordination polymers, [Co(azbbpy)(4,4'-bipy)0.5(DMF)(NCS)2]·MeOH (1) and [Co(azbbpy)(bpe)0.5(DMF)(NCS)2]·0.25H2O (2), resulted from the assembling of cobalt(II) ions by 1,3-bis(4-pyridyl)azulene, using either 4,4'-bipyridyl or 1,2-bis(4-pyridyl)ethylene as neutral spacers. The cobalt(II) nodes in 1 and 2 act as single-ion magnets (SIMs).

chemistry.chemical_classificationEthyleneSingle ionchemistry.chemical_elementPolymerAzuleneIonInorganic Chemistrychemistry.chemical_compoundchemistryMagnetOrganic chemistryPhysical chemistryPhysical and Theoretical ChemistryCobaltInorganic Chemistry
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Trinuclear Nickel(II) and Cobalt(II) Complexes Constructed from Mannich–Schiff‐Base Ligands: Synthesis, Crystal Structures, and Magnetic Properties

2019

Inorganic Chemistrychemistry.chemical_compoundNickelSchiff basechemistryPolymer chemistrychemistry.chemical_elementCrystal structureCobaltEuropean Journal of Inorganic Chemistry
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A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [FeIII{HB(pz)3}(CN)3]− and LnIII ions: synthesis, …

2021

A new series of cyanido-bridged {FeIIILnIII}2 neutral molecular squares of general formula [Fe{HB(pz)3}(CN)(μ-CN)2Ln(NO3)2(pyim)(Ph3PO)]2·2CH3CN [Ln = Ce (1), Pr (2), Nd (3), Gd (4), Tb (5), Dy (6) and Er (7); {HB(pz)3}− = hydrotris(pyrazolyl)borate, pyim = 2-(1H-imidazol-2-yl)pyridine and Ph3PO = triphenylphosphine oxide] were obtained by reacting the low-spin [Fe{HB(pz)3}(CN)3]− species with the preformed [LnIII(pyim)(NO3)2(pyim)(Ph3PO)]+ complex anions (generated in situ by mixing the nitrate salt of each Ln(III) ion with pyim and Ph3PO molecules). Single-crystal X-ray diffraction studies show that 1–7 are isostructural compounds that crystallize in the triclinic P space group. Their cry…

Inorganic ChemistryLanthanideLigand field theoryCrystallographyMaterials scienceOctahedronSupramolecular chemistryMoleculeCrystal structureIsostructuralMagnetic susceptibilityDalton Transactions
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Copper(II) complexes with 1,5-bis(2-hydroxybenzaldehyde)carbohydrazone

2014

Abstract The acid–base properties of 1,5-bis(2-hydroxybenzaldehyde)carbohydrazone (H4L) and its thioanalogue 1,5-bis(2-hydroxybenzaldehyde)thiocarbohydrazone (H4LS) have been studied experimentally by pH-potentiometry and UV–Vis spectrophotometry and theoretically by using DFT methods. Copper(II) complexes [Cu2(HL)(DMSO)2(H2O)]NO3·H2O (1), [{Cu2(HL)(DMF)(H2O)}n][{Cu2(HL)(DMF)NO3}n](NO3)n (2), [Cu2(HL)(DMF)2(H2O)]HSO4·H2O (3), [Cu2(HL)(DMF)2(H2O)][Cu2(HL)(SO4)(H2O)(DMF)2]·2H2O (4) and [Cu4(HL)2(HSO4)(DMF)2]HSO4 (5), where H4L = 1,5-bis(2-hydroxybenzaldehyde)carbohydrazone, have been synthesised. Complexes 1–3 have been characterised by elemental analysis, IR spectroscopy, ESI mass spectromet…

Schiff basemedicine.diagnostic_testLigandStereochemistryInfrared spectroscopychemistry.chemical_elementMagnetic susceptibilityCopperInorganic Chemistrychemistry.chemical_compoundCrystallographyDeprotonationchemistrySpectrophotometryMaterials ChemistrymedicinePhysical and Theoretical ChemistryCyclic voltammetryPolyhedron
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CCDC 1825561: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-gadolinium(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
researchProduct

CCDC 1582396: Experimental Crystal Structure Determination

2018

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G

Space GroupCrystallographytetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-terbium(iii) hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1520091: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-hexakis(mu-cyano)-tetrakis(110-phenanthroline)-decacyano-diaqua-di-copper(ii)-tetra-chromium(iii)-di-manganese(ii) acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 978467: Experimental Crystal Structure Determination

2014

Related Article: Diana Dragancea, Sergiu Shova, Eva A. Enyedy, Martin Breza, Peter Rapta, Luca M. Carrella, Eva Rentschler, Anatolie Dobrov, Vladimir B. Arion|2014|Polyhedron|80|180|doi:10.1016/j.poly.2014.03.039

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~2~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-(nitrato)-(NN-dimethylformamide)-di-copper(ii) (mu~2~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-(aqua)-(NN-dimethylformamide)-di-copper(ii) nitrate monohydrate]Experimental 3D Coordinates
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CCDC 1969476: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographytetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-dysprosium-di-iron acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1986756: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-cyano)-bis(2-methylpyrazine)-iron(ii)-di-silver(i)]Experimental 3D Coordinates
researchProduct

CCDC 1482464: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-(S)-(2-(((2'-((2-oxy-3-methoxybenzylidene)amino)-11'-binaphthalen-2-yl)imino)methyl)-6-methoxyphenolato))-bis(mu-methoxo)-di-manganese(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
researchProduct

CCDC 1520092: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographycatena-((mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tris(mu-cyano)-pentacyano-bis(1-(pyridin-2-yl)methanamine)-copper(ii)-di-chromium(iii)-manganese(ii) acetonitrile solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049500: Experimental Crystal Structure Determination

2015

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hexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-europium-hexa-zinc dimethylformamide solvate hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2096753: Experimental Crystal Structure Determination

2021

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bis[bis(1-methyl-1H-imidazol-2-yl)methanone]-bis(isoselenocyanato)-cobaltSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1049932: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyhexakis(mu2-Acetato)-hexakis(mu2-oxalato)-hexakis(mu2-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexa-dysprosium-hexa-zinc methanol solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957553: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-azido)-dinitrato-tri-nickelExperimental 3D Coordinates
researchProduct

CCDC 2044634: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-246-tris({[2-(dimethylamino)ethyl]imino}methyl)benzene-135-triolato)-tris(mu-benzene-1245-tetracarboxylato)-dodeca-copper(ii) unknown solvate]Experimental 3D Coordinates
researchProduct

CCDC 1049499: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyhexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-dysprosium pentahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957556: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-nitrato)-dinitrato-tri-cobalt acetonitrile solvateExperimental 3D Coordinates
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CCDC 1969477: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-erbium-di-iron acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 978468: Experimental Crystal Structure Determination

2014

Related Article: Diana Dragancea, Sergiu Shova, Eva A. Enyedy, Martin Breza, Peter Rapta, Luca M. Carrella, Eva Rentschler, Anatolie Dobrov, Vladimir B. Arion|2014|Polyhedron|80|180|doi:10.1016/j.poly.2014.03.039

Space GroupCrystallographyCrystal System(mu~2~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-aqua-bis(NN-dimethylformamide)-di-copper(ii) hydrogen sulfate monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2073773: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-gadolinium(iii)-iron(iii) acetonitrile solvate]Experimental 3D Coordinates
researchProduct

CCDC 1049501: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu3-11'-Pyridine-26-diylbis(3-oxobut-1-en-1-olato))-(mu2-oxalato)-octa-aqua-bis(oxalato)-tetra-nickel-di-gadolinium docosahydrateExperimental 3D Coordinates
researchProduct

CCDC 1907945: Experimental Crystal Structure Determination

2019

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tetrakis(mu-cyano)-tetranitrato-dicyano-bis(triphenylphosphine oxide)-bis(2-(pyridin-2-yl)imidazolyl)-bis(hydrogen tris(pyrazolyl)borate)-di-iron-di-samarium acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1969470: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-cerium-di-iron acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1049546: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexakis(ethanol)-hexa-dysprosium-hexa-nickel acetonitrile solvate hydrateExperimental 3D Coordinates
researchProduct

CCDC 940301: Experimental Crystal Structure Determination

2013

Related Article: Alina S. Dinca, Julia Vallejo, Sergiu Shova, Francesc Lloret, Miguel Julve and Marius Andruh|2013|Polyhedron|65|238|doi:10.1016/j.poly.2013.08.049

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu~3~-3-[(Hydroxyimino)methyl]-2-oxidobenzoate)-hexakis(mu~3~-2-oxido-3-[(oxidoimino)methyl]benzoate)-dodecakis(NN-dimethylformamide)-(hexaaqua)-hexa-dysprosium-hexa-zinc NN-dimethylformamide solvate hydrateExperimental 3D Coordinates
researchProduct

CCDC 1582395: Experimental Crystal Structure Determination

2018

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tetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-dysprosium(iii) tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2073771: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-dysprosium(iii)-iron(iii) acetonitrile solvate]Experimental 3D Coordinates
researchProduct

CCDC 2096752: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[bis(1-methyl-1H-imidazol-2-yl)methanone]-bis(isothiocyanato)-cobaltExperimental 3D Coordinates
researchProduct

CCDC 1567349: Experimental Crystal Structure Determination

2017

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(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-erbium-tungsten dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 978469: Experimental Crystal Structure Determination

2014

Related Article: Diana Dragancea, Sergiu Shova, Eva A. Enyedy, Martin Breza, Peter Rapta, Luca M. Carrella, Eva Rentschler, Anatolie Dobrov, Vladimir B. Arion|2014|Polyhedron|80|180|doi:10.1016/j.poly.2014.03.039

Space GroupCrystallography(mu~2~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-aqua-bis(NN-dimethylformamide)-di-copper(ii) (mu~2~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-sulfato-aqua-bis(NN-dimethylformamide)-di-copper(ii) dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1969471: Experimental Crystal Structure Determination

2021

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tetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-neodymium acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2073772: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-terbium(iii)-iron(iii) acetonitrile solvate]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 953096: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-aqua-(nitrato)-bis(cyano)-nickel-terbium-tungsten acetonitrile solvate hydrate]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1574907: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-tetracyano-bis(2-(1H-imidazol-2-yl)pyridine)-(22'-bipyridine)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v)]Experimental 3D Coordinates
researchProduct

CCDC 2073774: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographycatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-holmium(iii)-iron(iii) acetonitrile solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1825562: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systemdodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-dysprosium(iii) NN-dimethylformamide solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1878182: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-(mu-16-naphthyridine)-(16-naphthyridine)-iron(ii)-di-silver(i))
researchProduct

CCDC 1482465: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-(R)-(2-(((2'-((2-oxy-3-methoxybenzylidene)amino)-11'-binaphthalen-2-yl)imino)methyl)-6-methoxyphenolato))-bis(mu-methoxo)-di-manganese(iii) NN-dimethylformamide solvateExperimental 3D Coordinates
researchProduct

CCDC 1582397: Experimental Crystal Structure Determination

2018

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tetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-gadolinium(iii) hexahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 978470: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographybis(mu~4~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-bis(mu~3~-2-(2-oxidobenzylidene)-N-((2-oxidophenyl)methylidene)hydrazinecarbohydrazonato)-bis(mu~2~-hydrogen sulfato)-tetrakis(dimethylformamide)-octa-copper(ii) bis(hydrogen sulfate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957555: Experimental Crystal Structure Determination

2019

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Space GroupCrystallography(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-isothiocyanato)-dinitrato-tri-cobalt acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 953097: Experimental Crystal Structure Determination

2013

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, Miguel Julve, and Marius Andruh|2013|Inorg.Chem.|52|11627|doi:10.1021/ic4019794

Space GroupCrystallographyCrystal Systemcatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-nitrato-aqua-dicyano-dysprosium-nickel-tungsten acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2072597: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographycatena-(bis(mu-cyano)-(mu-25-bis(pyridin-2-yl)pyrazine)-aqua-hexacyano-(dimethyl sulfoxide)-(bis(1-methyl-1H-imidazol-2-yl)methanone)-tri-cobalt hydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1986758: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tetrakis(mu-cyano)-(2-methylpyrazine)-iron(ii)-di-silver(i)]Cell ParametersExperimental 3D Coordinates
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CCDC 1029369: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-bipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt methanol solvate dihydrate]Experimental 3D Coordinates
researchProduct

CCDC 1580964: Experimental Crystal Structure Determination

2018

Related Article: Mihaela I. Mocanu, Sergiu Shova, Frances Lloret, Miguel Julve, Marius Andruh|2018|J.Coord.Chem.|71|693|doi:10.1080/00958972.2018.1434877

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[(22-dimethylpropane-13-diyl)bis(azanylylidenemethylylidene)]diphenolato)-bis(111555-hexafluoroacetylacetonato)-copper(ii)-cobalt(ii)Experimental 3D Coordinates
researchProduct

CCDC 1875357: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-(11'-biphenyl)-44'-dicarboxylato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) hydrateExperimental 3D Coordinates
researchProduct

CCDC 1515780: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal System(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)(azanylylidene)methylylidene]}bis(46-di-t-butylphenolato))-(isothiocyanato)-manganese(iii) hydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049497: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systemhexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-europium dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1029370: Experimental Crystal Structure Determination

2015

Related Article: Adrian E. Ion, Simona Nica, Augustin M. Madalan, Sergiu Shova, Julia Vallejo, Miguel Julve, Francesc Lloret, Marius Andruh|2015|Inorg.Chem.|54|16|doi:10.1021/ic5025197

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-44'-Azulene-13-diyldipyridine)-bis(mu2-44'-ethene-12-diyldipyridine)-bis(NN-dimethylformamide)-tetrakis(isothiocyanato)-di-cobalt hydrate]Experimental 3D Coordinates
researchProduct

CCDC 1567346: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050

Space GroupCrystallographyCrystal System(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-gadolinium-tungsten dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957554: Experimental Crystal Structure Determination

2019

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Space GroupCrystallography(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-azido)-dinitrato-tri-cobaltCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1582340: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(hexakis(mu-cyano)-(mu-oxalato)-tetrakis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tetra-aqua-hexacyano-di-chromium-tetra-copper-tetra-manganese hexahydrate)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1585318: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographytetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-tetrakis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-di-iron(iii)-di-lanthanum(iii) decahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1875359: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal System(mu-but-2-enedioato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1049498: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal Structurehexakis(mu2-22'-(Propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexakis(mu2-acetato-OO')-hexakis(mu2-oxalato)-hexa-copper-hexa-gadolinium dimethylformamide solvate nonahydrateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1875358: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-benzene-14-dicarboxylato)-bis(22'-{(1133-tetramethyldisiloxane-13-diyl)bis[(propane-31-diyl)azanylidenemethanylidene]}bis(46-di-t-butylphenolato))-di-manganese(iii) dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1567347: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-terbium-tungsten dihydrateExperimental 3D Coordinates
researchProduct

CCDC 1567348: Experimental Crystal Structure Determination

2017

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(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-dysprosium-tungsten dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1969473: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-terbium acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1969472: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-gadolinium-di-iron acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 953098: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-aqua-(22'-bipyridine)-(nitrato)-bis(cyano)-nickel-gadolinium-tungsten acetonitrile solvate dihydrate]Experimental 3D Coordinates
researchProduct

CCDC 2054785: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-25-bis(pyridin-2-yl)pyrazine)-tetrakis(mu-cyano)-bis(22'-[ethane-12-diylbis(azanylylidenemethanylylidene)]diphenolato)-tetracyano-di-cobalt-di-manganese]Experimental 3D Coordinates
researchProduct

CCDC 978466: Experimental Crystal Structure Determination

2014

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Space GroupCrystallography(mu~2~-22'-(carbonylbis(hydrazin-2-yl-1-ylidenemethylylidene))diphenolato)-aqua-bis(dimethyl sulfoxide)-di-copper(ii) nitrate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1574908: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systemcatena-[tris(mu-cyano)-(mu-1024-dimethyl-36141720-pentaazatricyclo[20.3.1.1812]heptacosa-1(26)268(27)91113202224-decaene-2627-diolato)-(22'-bipyridine)-tricyano-copper(ii)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v) acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1878181: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-(mu-16-naphthyridine)-(16-naphthyridine)-iron(ii)-di-silver(i))
researchProduct

CCDC 1907944: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systemtetrakis(mu-cyano)-tetranitrato-dicyano-bis(triphenylphosphine oxide)-bis(2-(pyridin-2-yl)imidazolyl)-bis(hydrogen tris(pyrazolyl)borate)-di-iron-di-europium acetonitrile solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1580963: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systembis(mu-2-methoxy-6-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato)-bis(111555-hexafluoroacetylacetonato)-di-nickel(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1957552: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-[propane-13-diylbis(azanylylidenemethanylylidene)]bis[4-bromo-6-({[2-(dimethylamino)ethyl](methyl)amino}methyl)phenolato])-bis(mu-nitrato)-dinitrato-tri-nickel acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1580965: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[(22-dimethylpropane-13-diyl)bis(iminomethyl)]diphenolato)-bis(mu-methoxo)-bis(111555-hexafluoroacetylacetonato)-tetra-copper(ii)Experimental 3D Coordinates
researchProduct

CCDC 1825560: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structuredodecakis(mu-3-formyl-2-oxidobenzoato)-dodecakis(mu-hydroxo)-dodecakis(NN-dimethylformamide)-dodeca-europium(iii) NN-dimethylformamide solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1510890: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(22'-[ethane-12-diylbis(azanylylidenemethylylidene)]diphenolato)-(29-dimethyl-110-phenanthroline)-bis(mu-cyano)-cyano-cobalt(ii)-manganese(iii) dihydrate]
researchProduct

CCDC 1969475: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-praseodymium acetonitrile solvateExperimental 3D Coordinates
researchProduct