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RESEARCH PRODUCT
Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain
Miguel JulveMaria-gabriela AlexandruDiana VisinescuSergiu ShovaFrancesc Lloretsubject
010405 organic chemistryStereochemistryCyanideCrystal structure010402 general chemistry01 natural sciencesInductive coupling0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryChain (algebraic topology)Ferrimagnetismdescription
The assembly reaction between the low-spin [CoII(dmphen)(CN)3]- metalloligand and the [MnIII(salen)(H2O)]+ complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n (1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = -1.71(1) cm-1.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | Dalton Transactions |